[1]贾坤*,徐明珍,潘海,等.耐高温腈基聚合物及复合材料研究进展[J].中国材料进展,2015,(12):031-35.[doi:10.7502/j.issn.1674-3962.2015.12.05]
　JIA Kun*,XU Mingzhen,PAN Hai,et al.Research Progress of High Temperature Resistant Phthalonitrile-based Polymers and Composites[J].MATERIALS CHINA,2015,(12):031-35.[doi:10.7502/j.issn.1674-3962.2015.12.05]
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耐高温腈基聚合物及复合材料研究进展()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
期数:
2015年第12期
页码:
031-35
栏目:
特约研究论文
出版日期:
2015-12-25

文章信息/Info

Title:
Research Progress of High Temperature Resistant Phthalonitrile-based Polymers and Composites
作者:
贾坤*; 徐明珍; 潘海; 王子成; 邹兴强; 姜明莉; 刘孝波
电子科技大学微电子与固体电子学院，耐高温高分子及复合材料四川省重点实验室
Author(s):
JIA Kun*;  XU Mingzhen;  PAN Hai;  WANG Zicheng;  ZOU Xingqiang;  JIANG Mingli;  LIU Xiaobo*
Research Branch of Functional Materials, Institute of Microelectronic & Solid State Electronic, High-Temperature Resistant Polymers and Composites Key Laboratory of Sichuan Province, University of Electronic Science and Technology of China
关键词:
腈基聚合物; 耐高温; 复合材料; 改性; 功能化
DOI:
10.7502/j.issn.1674-3962.2015.12.05
文献标志码:
A
摘要:
耐高温腈基聚合物是通过邻苯二甲腈类单体在高温下的加成聚合反应而得到的一系列高性能热固性树脂的统称，因此也被称为邻苯二甲腈树脂。由于其具备优异的高温力学性能、热（氧）稳定性、耐腐蚀性、阻燃性及良好的加工性能，邻苯二甲腈树脂在航空航天、船舶制造、微电子工业等高科技领域内展现出广泛的应用前景。本文首先简要介绍了邻苯二甲腈树脂的基本结构与热聚合机理；其次重点阐述了不同结构的邻苯二甲腈单体在固化剂作用下的热固化行为，明确了邻苯二甲腈树脂结构与性能的关系；随后分别介绍了邻苯二甲腈树脂的结构改性、加工性能、纤维增强复合材料的制备与性能研究、邻苯二甲腈聚合物的电磁功能化技术途径；最后简要分析了耐高温腈基聚合物及复合材料目前所面临的技术瓶颈并探索了未来的发展方向。
Abstract:
High temperature resistant nitrile-based polymers, also named as phthalonitrile resins, are high performance thermosets obtained by the addition polymerization of phthalonitrile monomers. Due to their outstanding high temperature mechanical properties, (oxidative) thermal stability, corrosion resistance, fire resistance and good processability, phthalonitrile resins have been widely used in various high-tech fields such as aerospace, microelectronics, ship manufacture, etc. In this review article, the basic chemical structures and thermal polymerization mechanism of bisphthalonitrile resins were firstly introduced, then the thermal curing reaction of various different phthalonitrile monomers in the presence of curing agent was discussed to clarify the structure and properties of bisphthalonitrile resins.     Furthermore, the structural modification, processability, preparation and properties of fiber reinforced composites, electro-magnetic functionalization for phthalonitrile-based polymers were introduced. The review ends a brief outlook of the future directions and prospects of the research area.
更新日期/Last Update: 2015-11-23