[1]孙维朋,顾竹灵,高占臣,等.不饱和聚碳硅烷的研究进展[J].中国材料进展,2018,(3):018-24.[doi:10.7502/j.issn.1674-3962.2018.03.03]
 SUN Weipeng,GU Zhuling,GAO Zhanchen,et al.Recent Advances of Unsaturated Polycarbosilane[J].MATERIALS CHINA,2018,(3):018-24.[doi:10.7502/j.issn.1674-3962.2018.03.03]
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不饱和聚碳硅烷的研究进展



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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
期数:
2018年第3期
页码:
018-24
栏目:
特约研究论文
出版日期:
2018-03-31

文章信息/Info

Title:
Recent Advances of Unsaturated Polycarbosilane
作者:
孙维朋 顾竹灵高占臣吕素芳蒋剑雄张飞豹
杭州师范大学? 有机硅化学及材料技术教育部重点实验室
Author(s):
SUN Weipeng GU Zhuling GAO Zhanchen LV Sufang JIANG Jianxiong ZHANG Feibao
Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 310012, China)



关键词:
不饱和聚碳硅烷硅氢加成共轭基团聚合物有机电致发光
Keywords:
unsaturated polycarbosilane hydrosilylation conjugated groups polymer organic electroluminescence
DOI:
10.7502/j.issn.1674-3962.2018.03.03
文献标志码:
A
摘要:
不饱和聚碳硅烷因其主链结构中具有硅和共轭基团交错的结构,具有良好的热稳定性、可溶性、易加工、低毒性等系列重要的物理和化学性质,使其在半导体材料、有机电致发光材料、陶瓷前驱体,耐热材料,光伏材料等诸多领域显示出广阔的应用前景,因此针对不饱和聚碳硅烷的研究一直是有机硅高分子领域的研究热点。本文总结了近年来不饱和聚碳硅烷的研究进展,对不饱和聚碳硅烷的合成方法进行了详细综述,包括硅氢加成反应, HECK 反应及Wittig 反应等,并介绍了不饱和聚碳硅烷在光电材料,电致发光等方面的应用情况。
Abstract:
Unsaturated polycarbosilanes composed of silicon and conjugated groups have been ideal and promising candidate for semiconductors, organic electroluminescence, ceramic precursors, heat-resistant materials and photovoltaic materials, due to their high thermal stability, good solubility, easy processability and low toxicity attributes. Therefore, unsaturated polycarbosilanes have long been the research focus in the field of silicone materials. This paper firstly summarizes the recent research progress and synthesis methods of unsaturated polycarbosilanes, including hydrosilylation reaction, Suzuki-Heck reaction and Wittig reaction. Then the application of unsaturated polycarbosilanes in photovoltaic and organic electroluminescence, are introduced.
更新日期/Last Update: 2018-02-28