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Metal-Organic Frameworks (MOFs) in Photocatalytic Organic Transformations(PDF)

MATERIALS CHINA[ISSN:1674-3962/CN:61-1473/TG]

Issue:
2017年第10期
Page:
41-45
Research Field:
前沿综述
Publishing date:

Info

Title:
Metal-Organic Frameworks (MOFs) in Photocatalytic Organic Transformations
Author(s):
SUN Dengrong LI Zhaohui
Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University,
Keywords:
metal-organic frameworks photocatalysis multifunctional material organic transformation CO2 reduction post-modification
CLC:

PACS:
-
DOI:
10.7502/j.issn.1674-3962.2017.10.09
DocumentCode:

Abstract:
The ever increasing global demand for energy has stimulated a new wave of research activity on efficient utilization of solar energy. Photocatalysis is a promising pathway in the direct transformation of solar energy to chemical energy and has attracted increasing attention. Metalorganic frameworks (MOFs), which have both of the characteristics of semiconductor and zeolite, have emerged as a new kind of potential photocatalyst. After years of development, MOFs have been used in a variety of photocatalytic applications, such as hydrogen evolution, environmental remediation and organic transformations. Among these various applications, the use of MOFs in photocatalytic organic transformations has become the focus of current research. In this review, we summarized the recent progress towards the application of MOFs in photocatalytic organic transformations including CO2 reduction, redox reactions and some complex lightinduced organic reactions like tandem reaction and CC coupling reaction. New strategies to improve the photocatalytic efficiency of MOFs were illustrated. We also provided a detailed discussion on the development of MOFs as a kind of multifunctional photocatalysts. Finally, the existing problems and the opportunities as well as the challenges of MOFs in this field were also evaluated and anticipated.

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Last Update: 2017-11-03