In recent years, dental caries which seriously effect the quality of people’s life have developed into the third major non-communicable diseases, Repairing damaged teeth is an important way to treat dental caries. Thus the development of dental restorative materials have attracted much attention. Because of its excellent mechanical properties, good biological compatibility, composite resin gradually walk into the sight of scientists as dental restorative materials. In order to treat dental caries effectively, large numbers of dental repair resin materials have been developed, some of which have been put into practice on clinical application. With the rapid development of nanotechnology, nano composite materials constructing by organic/inorganic hybrid technology have attracted much attention as a special class of dental restorative resin materials. This paper is based on the dental restorative resin materials, reviewing the development of various dental restorative materials briefly, emphatically introducing the research status of nano composite dental restorative material, which using visible light curing prepared by hybrid technique, showing the problem of dental restorative resin material and prospecting its future development.