[1]欧阳静,金娇,李晓玉,等.氧化锆(ZrO2)的电、光性质与应用[J].中国材料进展,2014,(8):056-59.[doi:10.7502/j.issn.1674-3962.2014.08.07]
　OUYANG Jing*,JIN Jiao,Li Xiaoyu,et al.Electronic and optical properties of zirconia(ZrO2) and their applications[J].MATERIALS CHINA,2014,(8):056-59.[doi:10.7502/j.issn.1674-3962.2014.08.07]
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氧化锆(ZrO2)的电、光性质与应用()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
期数:
2014年第8期
页码:
056-59
栏目:
前沿综述
出版日期:
2014-08-31

文章信息/Info

Title:
Electronic and optical properties of zirconia(ZrO2) and their applications
作者:
欧阳静; 金娇; 李晓玉; 杨华明; 周正
 南大学 资源加工与生物工程学院 无机材料系
Author(s):
OUYANG Jing*;  JIN Jiao;  Li Xiaoyu;  YANG Hua-ming*
Department of Inorganic Materials, School of Minerals Processing & Bioengineering, Central South University
关键词:
光学谱; 氧空位; 能带结构; 高温传导性
DOI:
10.7502/j.issn.1674-3962.2014.08.07
文献标志码:
A
摘要:
本文重点分析了ZrO2的电子结构与能带特点、光学吸收、发射谱等，指出ZrO2在光学领域可用于发光材料，也可以作为发光中心的基质，归纳了ZrO2发光的来源在于氧空位形成的F-色心或其缔合中心。引用第一原理计算的不同晶型ZrO2的电子构型和能带结构，说明了其电性质的特点，分析了高温下ZrO2的导电性质，说明了高温导电性的应用领域。
Abstract:
We reviewed in this part the band structutr, optical absorption and emission spectra of ZrO2, pointing out that ZrO2 can be used as luminescent material and base for luminescent centers, introducing that the luminescence in ZrO2 is originated from the F-centers constructed by oxygen vacancies and their combined centers. The electronic and band structures of ZrO2 with different crystallographic types were introduced based on the first principal calculations. Electronic conductive performances of zirconia at high temperatures were analyzed and their application fields were also introduced.
更新日期/Last Update: 2014-09-02