[1]曹慧军,张昕,韩金,等.高固体分环氧海洋防腐蚀涂料的研究进展[J].中国材料进展,2014,(1):020-25.[doi:10.7502/j.issn.1674-3962.2014.01.04]
　Cao Huijun,Zhang Xin,Han Jin,et al.Research and Progress of High Solid Epoxy Corrosion Resistant Coating[J].MATERIALS CHINA,2014,(1):020-25.[doi:10.7502/j.issn.1674-3962.2014.01.04]
点击复制

高固体分环氧海洋防腐蚀涂料的研究进展()
分享到：

中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
期数:
2014年第1期
页码:
020-25
栏目:
特约研究论文
出版日期:
2014-01-31

文章信息/Info

Title:
Research and Progress of High Solid Epoxy Corrosion Resistant Coating
文章编号:
1674—3962 (2009)01-
作者:
曹慧军1; 张昕1; 韩金1; 李红良2; 乌学东1
(1.中国科学院宁波材料技术与工程研究所,中科院海洋新材料与应用技术重点实验室,浙江省海洋材料与防护技术重点实验室,浙江 宁波 3152012）（2.宁波大达化学有限公司,浙江 宁波 315204.)
Author(s):
Cao Huijun1;  Zhang Xin1;  Han Jin1;  Li Hongliang2;  Wu Xuedong1
(1.Key Laboratory of Marine New Materials and Related Technology, Zhejiang Key Laboratory of Marine Materials and Protection Technology, Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo, 315201, P.R.China）（2.Ningbo Dada chemical co., LTD, Ningbo 315040 China)
关键词:
高固体分; 环氧涂料; 防腐蚀; 厚膜
分类号:
TG 146.4
DOI:
10.7502/j.issn.1674-3962.2014.01.04
文献标志码:
A
摘要:
海洋环境中，钢结构的腐蚀不可避免，有机涂层是一种延缓金属的腐蚀最有效、经济的材料之一。其中高固体分环氧涂料由于绿色环保、涂层致密性好、可厚涂等特点在海洋重防腐中得到广泛的应用。本文就目前高固体分环氧厚膜、超厚膜涂料的研究进展，其存在的问题及解决方法做了详细的介绍。其中，环氧树脂、胺类固化剂作为环氧涂料中的主要的成膜物质，对涂层的性能起着关键的作用。总结了几种在高固体分环氧涂料中切实可行的环氧树脂增韧改性方法，同时指出开发耐冲击性能优异，耐高温，低温固化、水下固化的环氧固化剂也是环氧固化剂的发展趋势。通过曼尼希碱改性合成的环氧固化剂，恰好能满足各种性能的要求，本文中阐述了该类环氧固化剂的合成研究进展状况。
Abstract:
In the marine environment, the corrosion of steel structures is inevitable. The organic coating is the most effective, economical and widespread way to slow down the metal corrosion. High solid epoxy coating has been widely used in heavy duty anticorrosion area due to its green feature, good compactness and high thickness. In this review, the progress of the high solid epoxy coating, the existing problems and the appropriate solutions are described in detail. The epoxy resin and amine curing agent for film formation play a key role in the properties of the coating. A series of practical methods of toughening epoxy resin for high solid epoxy coating has been summarized. Besides, impact and thermo resistant, and low temperature and underwater curing agent should be developed. The mannich base type epoxy resin curing agents can meet various performance requirements. This paper describes the research progress in the synthesis of the mannich base type curing agents

参考文献/References:

References
[1] Zhang Chengtao(张成涛),Liu Zonglin(刘宗林),Liu Weiyun(刘蔚云). 重防腐蚀涂料的应用与发展[J]. Total Corrosion Control(全面腐蚀控制), 1997,11(4):19-25
[2] Cheng Zhengtao(陈正涛). 无溶剂厚膜型环氧重防腐涂料的研究[J]. Moder Paint&Finishing (现代涂料与涂装), 2006,7(4):10-12.
[3] Almeida E.,Santos D.,Fragata F., et al. Anticorrosive painting for a wide spectrum of marine atmospheres: Environmental-friendly versus traditional paint systems[J]. Progress in Organic Coatings, 2006,57:11-22.
[4] Guo guanglin(郭光琳),Liu Rui(刘锐),Cheng Wang(程望). 重防腐蚀涂料的技术发展状况及环保要求[J]. Hebei Chemical Engineering and Industry(河北化工), 2001,(3):6-8.
[5] Du Jianwei(杜建伟),Zhang Jing(张静),Zhang Liping(张丽萍), et al. 无溶剂环氧玻璃鳞片涂料的研制[J]. Moder Paint&Finishing(现代涂料与涂装), 2011,14(6):8-11.
[6] Zhang Bin(张斌),Yu Xiaoyin(于晓颖),Meng Qingpeng(孟庆鹏). 无溶剂环氧涂料在石化行业中的应用[J]. Shanghai Coatings(上海涂料), 2008,46(6):40-43.
[7] Du Jianwei(杜建伟),Zhang Jing(张静),Liang Hao(梁镐), et al. 超厚膜无溶剂环氧涂料的研制[J]. Paint & Coatings Industry(涂料工业), 2007,37(2):8-9.
[8] Wang Xiujuan(王秀娟),Li Min(李敏),Ma Shengjun(马胜军). 高固体分环氧防腐涂料的制备[J]. Coatings Technology & Abstracts(涂料技术与文摘), 2010,(10):8-10.
[9] Guo Xiaojun(郭晓军),Bai Jing(白晶),Zhang Liping(张丽萍). 厚涂耐磨无溶剂环氧防腐涂料的研制[J]. Paint & Coatings Industry (涂料工业), 2008,38(7):6062.
[10] Song Guanwu(宋官武),Sheng Jianrong(沈建荣),Cai Qishang(蔡启上), et al.超厚膜涂料的应用[J]. Paint & Coatings Industry(涂料工业), 1999,29(3):24-25.
[11] Jiang Xiujie(姜秀杰),Cui Xianlin(崔显林). 海洋浪溅区钢结构超厚膜环氧涂料[J]. Shanghai Coatings(上海涂料), 2010,48(1):12-14.
[12] Jiang Jianming(蒋健明),Chen Zhengtao(陈正涛). 厚膜型无溶剂环氧重防腐涂料的研究[J]. Moder Paint&Finishing(现代涂料与涂装), 2006,7(4):10-12.
[13] Liu Zhi(刘志),Yang Xiaogang(杨晓刚). 超厚膜环氧重防腐涂料的耐中性盐雾性能研究[J]. Paint & Coatings Industry(涂料工业), 2009,39(3):57-60.
[14] Shi Mingsheng(石敏先),Huang Zhixiong(黄志雄). 端羧基丁腈橡胶改性环氧树脂的结构与性能[J]. Polymer Materials Science & Engineering(高分子材料科学与工程), 2008,24(2):47-50.
[15] Yao Xingfang(姚兴芳),Zhang Shifeng(张世锋)，Li Junwei(李军伟). 端羧基液体丁腈橡胶改性环氧结构胶的研究[J]. Thermosetting Resin(热固性树脂)， 2008,23(2):33-36.
[16] Huang Wenlin(黄文霖),Shang Guorong(单国荣),Weng Zhixue(翁志学).双酚A及端羧基丁腈橡胶对环氧树脂的增韧作用[J]. China Synthetic Rubber Industry(合成橡胶工业), 2007,30(2):119-123.
[17] Maazouz A,Sautereau H ,Gerard J K. Toughening of Epoxy Networks Using Preformed Core-Shell Particles or Reactive Rubbers[J]. Polymer Bulletin, 1994,33(01):67-74 .
[18] Ramos V D,da Costa H M,Soares V L P. Modification of epoxy resin: a comparison of different types of elastomer[J]. Polymer Testing,2005,24(03):387-394
[19] Kunz S C. Morphology and toughness characterization of epoxy resins modified with amine and carboxyl terminated rubbers[J], Polymer, 1982,23(13):1897-1906.
[20] Cheng Jianjun(陈建君),Jiang Zhiguo(姜志国). 端胺基聚氨酯增韧环氧树脂的研究[J], JOURNAL OF BEIJ ING UNIVERSITY OF CHEMICAL TECHNOLOGY(北京化工大学学报), 2006,3(6):66-70.
[21] Kaynak C,Celikbilek C,Akovlai G. Use of silane coupling agents to improve epoxy-rubber interface[J]. European Polymer Jounnal,2003,(39):1125-1132.
[22] Hong Xiaobing(洪晓斌),Xie Kai(谢凯),Xiao Jiayu(肖加余), et al. 有机硅改性双酚F环氧树脂的性能[J]. Polymer Materials Science & Engineering (高分子材料科学与工程), 2008,(2):59-62.
[23] Su Qiangqiang(苏倩倩),Liu Weiqu(刘伟区),Hou Menghua(侯孟华). 有机硅改性提高环氧树脂韧性和耐热性的研究[J]. Fine Chemicals(精细化工), 2008,25(1):31-34.
[24] Hou Yafeng(侯亚峰). 环氧树脂固化剂的发展现状与趋势[J]. Hebei Chemical Engineering and Industry (河南化工), 2010,27(4):5-6.
[25] Lu Guifang(鹿桂芳),Ding Yanbin(丁颜滨),Li Peijin(李佩瑾), et al. Mannich反应制备壬基酚改性胺固化剂[J]. Chemical Engineer(化学工程师),2001,(8):1-3．
[26] Song Daoli(宋道理),Xie Yuehui(谢跃辉),Xu Xiaowu(许晓武). 一种新型环氧树脂固化剂的合成与性能研究[J]. Chemistry and Adhesion(化学与黏合),2010,32(5):45-47.
[27] Dai Zhicheng(戴志晟). 环氧树脂用天然长链取代酚醛胺固化剂[J]. Paint & Coatings Industry(涂料工业), 2000,(8):1-4．
[28] Zhang Xingxi(张兴喜),Li Juan(李娟). 酚醛胺(T-31)环氧树脂固化剂之浅谈[J]. China Adhesive(中国胶粘剂), 2005,14(8):52—54．
[29] Yang Haiwang(杨海望). 我国曼尼希型环氧树脂固化剂的现状及发展预测[J]. Thermosetting Resin(热固性树脂),1997,(4):41-46．

备注/Memo

备注/Memo:
基金项目:国家自然科学基金资助项目（59493300）;教育部博士点基金资助项目（9800462）

更新日期/Last Update: 2014-01-02