[1]彭叔森,曾志翔,韩金,等.有机硅溶胶-凝胶防腐蚀涂层研究进展[J].中国材料进展,2014,(2):077-85.[doi:10.7502/j.issn.1674-3962.2014.02.02]
 PENG Shusen,ZENG zhixiang,CHEN Jianmin,et al.Progress of Anticorrosion Silane Based Sol-Gel Coating[J].MATERIALS CHINA,2014,(2):077-85.[doi:10.7502/j.issn.1674-3962.2014.02.02]
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有机硅溶胶-凝胶防腐蚀涂层研究进展()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
期数:
2014年第2期
页码:
077-85
栏目:
特约研究论文
出版日期:
2014-02-28

文章信息/Info

Title:
Progress of Anticorrosion Silane Based Sol-Gel Coating
文章编号:
1674—3962 (2009)01-
作者:
彭叔森曾志翔韩金陈建敏乌学东
(中国科学院宁波材料技术与工程研究所,中国科学院宁波海洋新材料与应用技术重点实验室,浙江省海洋材料与防护技术重点实验室,宁波 315201)
Author(s):
PENG Shusen ZENG zhixiang CHEN Jianmin WU Xuedong
(Key Laboratory of Marine New Materials and Related Technology, Zhejiang Key Laboratory of Marine Materials and Protection Technology, Ningbo Institute of Material Technology & Engineering, Chinese Academy of Sciences, Ningbo, 315201, P.R. China)
关键词:
防腐蚀溶胶-凝胶有机硅涂层
分类号:
TG 146.4
DOI:
10.7502/j.issn.1674-3962.2014.02.02
文献标志码:
A
摘要:
有机硅溶胶-凝胶涂层是指以烷基烷氧基硅烷为前驱体通过溶胶-凝胶技术制备的涂层。有机硅是分子水平上的有机-无机杂化分子,因此有机硅溶胶-凝胶涂层兼具了有机材料和无机材料的性能,并且能通过合理的调控有机和无机成分来获得所需的性能。其热稳定、耐刮擦性、与无机材料的结合性能明显高于普通的有机材料,柔韧性、与有机材料的结合性能明显高于一般的无机涂层。近年来,这种新型的、具有特殊性能的涂层被广泛研究用来保护金属材料(如铝、铁、镁、铜基材料)。本文从有机硅溶胶-凝胶涂层涉及的基本反应、硅烷在金属表面上的成键机理以及在不同金属上的应用等方面的研究进展进行了介绍,并展望了有机硅溶胶-凝胶涂层应用前景及未来的研究方向。
Abstract:
Silane based sol-gel coating refers to coating material prepared by sol-gel technique using alkyl alkoxy silane as precursor. Silane is a molecular level organic-inorganic hybrid molecule, therefore silane based sol-gel coating combines the properties of organic materials and inorganic materials, and can achieve desired properties through controlling organic and inorganic components. Its thermal stability, scratching resistant and adhesion to inorganic material are significantly higher than organic coating, its flexibility and adhesion to organic materials are remarkably higher than inorganic coating. Recently, this novel and special coating is widely used to protect metal materials such as aluminum, iron, magnesium and copper-based metals. This paper will introduce basic reactions in sol-gel process, the bond mechanism between silane and metal surface and application of silane based sol-gel coating on various metals. Recent research and future application of such coating will also discuss in the paper

参考文献/References:

References
[1] C.J. Brinker, G.W. Scherer. Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing [M]. New York: Academic Press, 1990.
[2] Huang Jianfeng(黄剑锋). Principle and Technology of Sol-Gel(溶胶-凝胶原理与技术) [M]. Beijing: Chemical Industry Press, 2005.
[3] M. Guglielmi. Sol-Gel Coatings on Metals [J]. Journal of Sol-Gel Science and Technology, 1997, 8 (1-3): 443-449.
[4] D. Wang, G.R. Bierwagen. Sol-Gel Coatings on Metals for Corrosion Protection [J]. Progress in Organic Coatings, 2009, 64 (4): 327-338.
[5] M.L. Zheludkevich, I.M. Salvado, M.G.S. Ferreira. Sol-Gel Coatings for Corrosion Protection of Metals [J]. Journal of Materials Chemistry, 2005, 15 (48): 5099-5111.
[6] C. Sanchez, G.J.D.A. Soler-Illia, F. Ribot, et al. Designed Hybrid Organic-Inorganic Nanocomposites from Functional Nanobuilding Blocks [J]. Chemistry of Materials, 2001, 13 (10): 3061-3083.
[7] J.Y. Wen, G.L. Wilkes. Organic/Inorganic Hybrid Network Materials by the Sol-Gel Approach [J]. Chemistry of Materials, 1996, 8 (8): 1667-1681.
[8] G. Schottner. Hybrid Sol-Gel-Derived Polymers: Applications of Multifunctional Materials [J]. Chemistry of Materials, 2001, 13 (10): 3422-3435.
[9] F. Mammeri, E. Le Bourhis, L. Rozes, et al. Mechanical Properties of Hybrid Organic-Inorganic Materials [J]. Journal of Materials Chemistry, 2005, 15 (35-36): 3787-3811.
[10] F.D. Osterholtz, E.R. Pohl. Kinetics of the Hydrolysis and Condensation of Organofunctional Alkoxysilanes: A Review [J]. Journal of Adhesion Science and Technology, 1992, 6 (1): 127-149.
[11] B. Arkles, J.R. Steinmetz, J. Zazyczny, et al. Factors Contributing to the Stability of Alkoxysilanes in Aqueous-Solution [J]. Journal of Adhesion Science and Technology, 1992, 6 (1): 193-206.
[12] Ebelmen. Untersuchungen ber Die Verbindungen Der Bors鋟re Und Kiesels鋟re Mit Aether [J]. Justus Liebigs Annalen der Chemie, 1846, 57 (3): 319-355.
[13] E. Konrad, O. B鋍hle, R. Signer. ber Polymere Kiesels鋟????reester. 19. Mitteilung ber Hochpolymere Verbindungen [J]. Justus Liebigs Annalen der Chemie, 1929, 474 (1): 276-295.
[14] H. Schmidt, H. Scholze, A. Kaiser. Principles of Hydrolysis and Condensation Reaction of Alkoxysilanes [J]. Journal of Non-Crystalline Solids, 1984, 63 (1-2): 1-11.
[15] F. Brunet. Polymerization Reactions in Methyltriethoxysilane Studied through Si-29 Nmr with Polarization Transfer [J]. Journal of Non-Crystalline Solids, 1998, 231 (1-2): 58-77.
[16] J.K. Premachandra, W.J. Van Ooij, J.E. Mark. Reaction Kinetics of Gamma-Ureidopropyltrimethoxysilane in the Water-Methanol System Studied by Ftir Spectroscopy [J]. Journal of Adhesion Science and Technology, 1998, 12 (12): 1361-1376.
[17] B. Riegel, S. Blittersdorf, W. Kiefer, et al. Kinetic Investigations of Hydrolysis and Condensation of the Glycidoxypropyltrimethoxysilane/Aminopropyltriethoxy-Silane System by Means of Ft-Raman Spectroscopy I [J]. Journal of Non-Crystalline Solids, 1998, 226 (1-2): 76-84.
[18] M. Pantoja, F. Velasco, D. Broekema, et al. The Influence of Ph on the Hydrolysis Process of Gamma-Methacryloxypropyltrimethoxysilane, Analyzed by Ft-Ir, and the Silanization of Electrogalvanized Steel [J]. Journal of Adhesion Science and Technology, 2010, 24 (6): 1131-1143.
[19] M. Kuniyoshi, M. Takahashi, Y. Tokuda, et al. Hydrolysis and Polycondensation of Acid-Catalyzed Phenyltriethoxysilane (Phtes) [J]. Journal of Sol-Gel Science and Technology, 2006, 39 (2): 175-183.
[20] B. Diaz-Benito, F. Velasco, F.J. Martinez, et al. Hydrolysis Study of Bis-1,2-(Triethoxysilyl)Ethane Silane by Nmr [J]. Colloids and Surfaces a-Physicochemical and Engineering Aspects, 2010, 369 (1-3): 53-56.
[21] T. Metroke, Y.M. Wang, W.J. van Ooij, et al. Chemistry of Mixtures of Bis- Trimethoxysilylpropyl Amine and Vinyltriacetoxysilane: An Nmr Analysis [J]. Journal of Sol-Gel Science and Technology, 2009, 51 (1): 23-31.
[22] Y. Dubitsky, A. Zaopo, G. Zannoni, et al. H-1 Nmr Study of the Hydrolysis of Vinyltrialkoxysilanes [J]. Materials Chemistry and Physics, 2000, 64 (1): 45-53.
[23] LI Fangwen (李方文), WU Jianfeng (吴建锋), XU Xiaohong (徐晓虹), et al. 丙基三甲氧基硅烷的水解 [J]. Chemical Industry and Engineering (化学工业与工程), 2008, 25 (3): 203-207.
[24] W. Van Ooij, D. Zhu, M. Stacy, et al. Corrosion Protection Properties of Organofunctional Silanes--an Overview [J]. Tsinghua Science & Technology, 2005, 10 (6): 639-664.
[25] E.R. Pohl, A. Chaves, Sterically Hindered Silanes for Waterborne Systems: A Model Study of Silane Hydrolysis [C]. Silanes and Other Coupling Agents Vol 3. United States: CRC Press, 2004: 3-9.
[26] G. Pan, D.W. Schaefer, W.J. van Ooij, et al. Morphology and Water Resistance of Mixed Silane Films of Bis 3-(Triethoxysilyl) Propyl Tetrasulfide and Bis- Trimethoxysilylpropyl Amine [J]. Thin Solid Films, 2006, 515 (4): 2771-2780.
[27] M. Gettings, A.J. Kinloch. Surface Analysis of Polysiloxane Metal Oxide Interfaces [J]. Journal of Materials Science, 1977, 12 (12): 2511-2518.
[28] S.J. Davis, J.F. Watts. Organization of Methoxysilane Molecules on Iron [J]. International Journal of Adhesion and Adhesives, 1996, 16 (1): 5-15.
[29] D. Susac, C.W. Leung, X. Sun, et al. Comparison of a Chromic Acid and a Btse Final Rinse Applied to Phosphated 2024-T3 Aluminum Alloy [J]. Surface & Coatings Technology, 2004, 187 (2-3): 216-224.
[30] M. Teo, J. Kim, P.C. Wong, et al. Pre-Treatments Applied to Oxidized Aluminum Surfaces to Modify the Interfacial Bonding with Bis-1,2-(Triethoxysilyl)Ethane (Btse) - Part I. High-Purity Al with Native Oxide [J]. Applied Surface Science, 2005, 252 (5): 1293-1304.
[31] J. Fang, B.J. Flinn, Y.L. Leung, et al. A Characterization of the Gamma-Glycidoxypropyltrimethoxysilane and Aluminium Interface by Sims and Xps [J]. Journal of Materials Science Letters, 1997, 16 (20): 1675-1676.
[32] R. Kasemann, H. Schmidt. Coatings for Mechanical and Chemical Protection Based on Organic-Inorganic Sol-Gel Nanocomposites [J]. New Journal of Chemistry, 1994, 18 (10): 1117-1123.
[33] M. Pilz, H. Romich. Sol-Gel Derived Coatings for Outdoor Bronze Conservation [J]. Journal of Sol-Gel Science and Technology, 1997, 8 (1-3): 1071-1075.
[34] S. Langenfeld, G. Jonschker, H. Schmidt. New Sol-Gel Based Coatings as Corrosion- and Wear-Protection on Non-Ferrous Metals [J]. Materialwissenschaft und Werkstofftechnik, 1998, 29 (1): 23-29.
[35] T.L. Metroke, R.L. Parkhill, E.T. Knobbe. Synthesis of Hybrid Organic-Inorganic Sol-Gel Coatings for Corrosion Resistance [J]. Organic/Inorganic Hybrid Materials II, 1999, 576: 293-298.
[36] S. Peng, Z. Zeng, W. Zhao, et al. Synergistic Effect of Thiourea in Epoxy Functionalized Silica Sol朑el Coating for Copper Protection [J]. Surface & Coatings Technology, 2012, 213: 1?75-192.
[37] A. Pepe, M. Aparicio, S. Cere, et al. Preparation and Characterization of Cerium Doped Silica Sol-Gel Coatings on Glass and Aluminum Substrates [J]. Journal of Non-Crystalline Solids, 2004, 348: 162-171.
[38] M. Sheffer, A. Groysman, D. Starosvetsky, et al. Anion Embedded Sol-Gel Films on Al for Corrosion Protection [J]. Corrosion Science, 2004, 46 (12): 2975-2985.
[39] J.H. Osborne, Y.J. Du, M. Damron, et al. Inorganic/Organic Hybrid Coatings for Aircraft Aluminum Alloy Substrates [J]. Progress in Organic Coatings, 2001, 41 (4): 226-232.
[40] J. Gallardo, A. Duran, J.J. de Damborenea. Electrochemical and in Vitro Behaviour of Sol-Gel Coated 316l Stainless Steel [J]. Corrosion Science, 2004, 46 (4): 795-806.
[41] A.N. Khramov, V.N. Balbyshev, L.S. Kasten, et al. Sol-Gel Coatings with Phosphonate Functionalities for Surface Modification of Magnesium Alloys [J]. Thin Solid Films, 2006, 514 (1-2): 174-181.
[42] Y.-S. Li, W. Lu, Y. Wang, et al. Studies of (3-Mercaptopropyl)Trimethoxylsilane and Bis(Trimethoxysilyl)Ethane Sol-Gel Coating on Copper and Aluminum [J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy, 2009, 73 (5): 922-928.
[43] A.L.K. Tan, A.M. Soutar. Hybrid Sol-Gel Coatings for Corrosion Protection of Copper [J]. Thin Solid Films, 2008, 516 (16): 5706-5709.
[44] A. Soutar, B. Rabaud, M. Qian, et al. Mechanical and Electrochemical Properties of Hybrid Sol-Gel Protective Coatings for Copper Substrates [J]. SIMTech technical reports, 2005, 6 (1): 50-54.
[45] D. Raps, T. Hack, J. Wehr, et al. Electrochemical Study of Inhibitor-Containing Organic-Inorganic Hybrid Coatings on Aa2024 [J]. Corrosion Science, 2009, 51 (5): 1012-1021.
[46] V. Barranco, N. Carmona, J.C. Galvan, et al. Electrochemical Study of Tailored Sol-Gel Thin Films as Pre-Treatment Prior to Organic Coating for Az91 Magnesium Alloy [J]. Progress in Organic Coatings, 2010, 68 (4): 347-355.
[47] P.S. Correa, C.F. Malfatti, D.S. Azambuja. Corrosion Behavior Study of Az91 Magnesium Alloy Coated with Methyltriethoxysilane Doped with Cerium Ions [J]. Progress in Organic Coatings, 2011, 72 (4): 739-747.
[48] N.C. Rosero-Navarro, S.A. Pellice, Y. Castro, et al. Improved Corrosion Resistance of Aa2024 Alloys through Hybrid Organic-Inorganic Sol-Gel Coatings Produced from Sols with Controlled Polymerisation [J]. Surface & Coatings Technology, 2009, 203 (13): 1897-1903.
[49] T.L. Metroke, O. Kachurina, E.T. Knobbe. Particle-Doped Organic-Inorganic Hybrid Coatings as Corrosion Inhibiting Surface Treatments for Aluminum Alloys [J]. Materials Research Society Symposium Proceedings, 2002, 726: 395-400.
[50] Y.-S. Li, T. Tran, Y. Xu, et al. Spectroscopic Studies of Trimetoxypropylsilane and Bis(Trimethoxysilyl)Ethane Sol-Gel Coatings on Aluminum and Copper [J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy, 2006, 65 (3-4): 779-786.
[51] S.S. Pathak, A.S. Khanna. Synthesis and Performance Evaluation of Environmentally Compliant Epoxysilane Coatings for Aluminum Alloy [J]. Progress in Organic Coatings, 2008, 62 (4): 409-416.
[52] N. Voevodin, D. Buhrmaster, V. Balbyshev, et al. Nonchromated Coating Systems for Corrosion Protection of Aircraft Aluminum Alloys [J]. Materials Performance, 2006, 45 (11): 48-51.
[53] M.S. Donley, R.A. Mantz, A.N. Khramov, et al. The Self-Assembled Nanophase Particle (Snap) Process: A Nanoscience Approach to Coatings [J]. Progress in Organic Coatings, 2003, 47 (3-4): 401-415.
[54] L.S. Kasten, V.N. Balbyshev, M.S. Donley. Surface Analytical Study of Self-Assembled Nanophase Particle (Snap) Surface Treatments [J]. Progress in Organic Coatings, 2003, 47 (3-4): 214-224.
[55] R. Zandi-zand, A. Ershad-langroudi, A. Rahimi. Silica Based Organic-Inorganic Hybrid Nanocomposite Coatings for Corrosion Protection [J]. Progress in Organic Coatings, 2005, 53 (4): 286-291.
[56] Z. Feng, Y. Liu, G.E. Thompson, et al. Sol-Gel Coatings for Corrosion Protection of 1050 Aluminium Alloy [J]. Electrochimica Acta, 2010, 55 (10): 3518-3527.
[57] R.L. Parkhill, E.T. Knobbe, M.S. Donley. Application and Evaluation of Environmentally Compliant Spray-Coated Ormosil Films as Corrosion Resistant Treatments for Aluminum 2024-T3 [J]. Progress in Organic Coatings, 2001, 41 (4): 261-265.
[58] N.P. Tavandashti, S. Sanjabi, T. Shahrabi. Corrosion Protection Evaluation of Silica/Epoxy Hybrid Nanocomposite Coatings to Aa2024 [J]. Progress in Organic Coatings, 2009, 65 (2): 182-186.
[59] T.L. Metroke, O. Kachurina, E.T. Knobbe. Spectroscopic and Corrosion Resistance Characterization of Glymo-Teos Ormosil Coatings for Aluminum Alloy Corrosion Inhibition [J]. Progress in Organic Coatings, 2002, 44 (4): 295-305.
[60] L.S. Kasten, J.T. Grant, N. Grebasch, et al. An Xps Study of Cerium Dopants in Sol-Gel Coatings for Aluminum 2024-T3 [J]. Surface & Coatings Technology, 2001, 140 (1): 11-15.
[61] A.N. Khramov, N.N. Voevodin, V.N. Balbyshev, et al. Hybrid Organo-Ceramic Corrosion Protection Coatings with Encapsulated Organic Corrosion Inhibitors [J]. Thin Solid Films, 2004, 447: 549-557.
[62] H.-w. Shi, F.-c. Liu, E.-h. Han. Characterization of Self-Assembled Nano-Phase Silane-Based Particle Coating [J]. Transactions of Nonferrous Metals Society of China, 2010, 20 (10): 1928-1935.
[63] A.N. Khramov, V.N. Balbyshev, R.A. Mantz, Protection of Aluminum Alloys Via Hybrid Sol-Gel Coatings with Encapsulated Organic Corrosion Inhibitors, in: W.J. Poole, M.A. Wells, D.J. Lloyd (Eds.) Aluminium Alloys 2006, Pts 1 and 2 - Research through Innovation and Technology, 2006, pp. 661-666.
[64] Y. Liu, D.Z. Sun, H. You, et al. Corrosion Resistance Properties of Organic-Inorganic Hybrid Coatings on 2024 Aluminum Alloy [J]. Applied Surface Science, 2005, 246 (1-3): 82-89.
[65] E. Roussi, A. Tsetsekou, D. Tsiourvas, et al. Novel Hybrid Organo-Silicate Corrosion Resistant Coatings Based on Hyperbranched Polymers [J]. Surface & Coatings Technology, 2011, 205 (10): 3235-3244.
[66] N.N. Voevodin, J.W. Kurdziel, R. Mantz. Corrosion Protection for Aerospace Aluminum Alloys by Modified Self-Assembled Nanophase Particle (Msnap) Sol-Gel [J]. Surface & Coatings Technology, 2006, 201 (3-4): 1080-1084.
[67] K.H. Wu, T.C. Chang, C.C. Yang, et al. Dynamics and Corrosion Resistance of Amine-Cured Organically Modified Silicate Coatings on Aluminum Alloys [J]. Thin Solid Films, 2006, 513 (1-2): 84-89.
[68] K.H. Wu, M.C. Li, C.C. Yang, et al. Domain Size and Thermal Stability of Amine-Cured Hybrid Films as Corrosion Resistance Treatments for Aluminum Alloy [J]. Journal of Non-Crystalline Solids, 2006, 352 (26-27): 2897-2904.
[69] M.S. Donley, V.N. Balbyshev, N.N. Voevodin. Self-Assembled Nanophase Particle (Snap) Surface Treatments for Corrosion Protection of Aa2024-T3 [J]. Progress in Organic Coatings, 2005, 52 (1): 34-38.
[70] A.J. Vreugdenhil, V.J. Gelling, M.E. Woods, et al. The Role of Crosslinkers in Epoxy-Amine Crosslinked Silicon Sol-Gel Barrier Protection Coatings [J]. Thin Solid Films, 2008, 517 (2): 538-543.
[71] A.N. Khramov, V.N. Balbyshev, N.N. Voevodin, et al. Nanostructured Sol-Gel Derived Conversion Coatings Based on Epoxy- and Amino-Silanes [J]. Progress in Organic Coatings, 2003, 47 (3-4): 207-213.
[72] A.J. Vreugdenhil, V.N. Balbyshev, M.S. Donley. Nanostructured Silicon Sol-Gel Surface Treatments for Al 2024-T3 Protection [J]. Journal of Coatings Technology, 2001, 73 (915): 35-43.
[73] T.L. Metroke, O. Kachurina, E.T. Knobbe. Spectroscopic and Corrosion Resistance Characterization of Amine and Super Acid-Cured Hybrid Organic-Inorganic Thin Films on 2024-T3 Aluminum Alloy [J]. Progress in Organic Coatings, 2002, 44 (3): 185-199.
[74] N.N. Voevodin, V.N. Balbyshev, M. Khobaib, et al. Nanostructured Coatings Approach for Corrosion Protection [J]. Progress in Organic Coatings, 2003, 47 (3-4): 416-423.
[75] A. Khramov, N.N. Voevodin, V.N. Balbyshev, et al. Sol-Gel-Derived Corrosion-Protective Coatings with Controllable Release of Incorporated Organic Corrosion Inhibitors [J]. Thin Solid Films, 2005, 483 (1-2): 191-196.
[76] K.A. Yasakau, M.L. Zheludkevich, O.V. Karavai, et al. Influence of Inhibitor Addition on the Corrosion Protection Performance of Sol-Gel Coatings on Aa2024 [J]. Progress in Organic Coatings, 2008, 63 (3): 352-361.
[77] M. Li, Y.Q. Yang, L. Liu, et al. Electro-Assisted Preparation of Dodecyltrimethoxysilane/Tio(2) Composite Films for Corrosion Protection of Aa2024-T3 (Aluminum Alloy) [J]. Electrochimica Acta, 2010, 55 (8): 3008-3014.
[78] P.C.R. Varma, B. Duffy, J. Cassidy. Influence of Magnesium Nitrate on the Corrosion Performance of Sol-Gel Coated Aa2024-T3 Aluminium Alloy [J]. Surface & Coatings Technology, 2009, 204 (3): 277-284.
[79] O. Kachurina, T.L. Metroke, E. Stesikova, et al. Comparison of Single and Multilayer Coatings Based on Ormosil and Conversion Layers for Aluminum Alloy Corrosion Inhibition [J]. Journal of Coatings Technology, 2002, 74 (926): 43-48.
[80] T.L. Metroke, A. Apblett. Effect of Solvent Dilution on Corrosion Protective Properties of Ormosil Coatings on 2024-T3 Aluminum Alloy [J]. Progress in Organic Coatings, 2004, 51 (1): 36-46.
[81] P.C.R. Varma, J. Colreavy, J. Cassidy, et al. Effect of Organic Chelates on the Performance of Hybrid Sol-Gel Coated Aa 2024-T3 Aluminium Alloys [J]. Progress in Organic Coatings, 2009, 66 (4): 406-411.
[82] P.C.R. Varma, J. Colreavy, J. Cassidy, et al. Corrosion Protection of Aa 2024-T3 Aluminium Alloys Using 3, 4-Diaminobenzoic Acid Chelated Zirconium-Silane Hybrid Sol-Gels [J]. Thin Solid Films, 2010, 518 (20): 5753-5761.
[83] M. Sheffer, A. Groysman, D. Mandler. Electrodeposition of Sol-Gel Films on Al for Corrosion Protection [J]. Corrosion Science, 2003, 45 (12): 2893-2904.
[84] A. Tiwari, J. Zhu, L.H. Hihara. The Development of Low-Temperature Hardening Silicone Ceramer Coatings for the Corrosion Protection of Metals [J]. Surface & Coatings Technology, 2008, 202 (19): 4620-4635.
[85] T. Lampke, S. Darwich, D. Nickel, et al. Development and Characterization of Sol-Gel Composite Coatings on Aluminum Alloys for Corrosion Protection [J]. Materialwissenschaft und Werkstofftechnik, 2008, 39 (12): 914-919.
[86] A. Pepe, P. Galliano, S. Cere, et al. Hybrid Silica Sol-Gel Coatings on Austempered Ductile Iron (Adi) [J]. Materials Letters, 2005, 59 (17): 2219-2222.
[87] P. Kiruthika, R. Subasri, A. Jyothirmayi, et al. Effect of Plasma Surface Treatment on Mechanical and Corrosion Protection Properties of Uv-Curable Sol-Gel Based Gpts-Zro(2) Coatings on Mild Steel [J]. Surface & Coatings Technology, 2010, 204 (8): 1270-1276.
[88] S.M.A. Hosseini, A.H. Jafari, E. Jamalizadeh. Self-Healing Corrosion Protection by Nanostructure Sol-Gel Impregnated with Propargyl Alcohol [J]. Electrochimica Acta, 2009, 54 (28): 7207-7213.
[89] S.M. Madani, M. Ehteshamzadeh, H.H. Rafsanjani. Investigation of the Microstructure and Corrosion Performance of a Nanostructured Titania-Containing Hybrid Silicate Film on Mild Steel [J]. Thin Solid Films, 2010, 519 (1): 145-150.
[90] S.S. Peng, W.J. Zhao, Z.X. Zeng, et al. Preparation of Anticorrosion Hybrid Silica Sol-Gel Coating Using Ce(No3)(3) as Catalyst [J]. Journal of Sol-Gel Science and Technology, 2013, 66 (1): 133-138.
[91] K. Joncoux-Chabrol, J.P. Bonino, M. Gressier, et al. Improvement of Barrier Properties of a Hybrid Sol-Gel Coating by Incorporation of Synthetic Talc-Like Phyllosilicates for Corrosion Protection of a Carbon Steel [J]. Surface & Coatings Technology, 2012, 206 (11-12): 2884-2891.
[92] J.G. Liu, G.P. Gong, C.W. Yan. Enhancement of the Erosion-Corrosion Resistance of Dacromet with Hybrid Sio2 Sol-Gel [J]. Surface & Coatings Technology, 2006, 200 (16-17): 4967-4975.
[93] A. Pepe, M. Aparicio, S. Cere, et al. Synthesis of Hybrid Silica Sol-Gel Coatings Containing Zn Particles on Carbon Steel and Al/Zn Coated Carbon Steel [J]. Materials Letters, 2005, 59 (29-30): 3937-3940.
[94] A. Pepe, P. Galliano, M. Aparicio, et al. Sol-Gel Coatings on Carbon Steel: Electrochemical Evaluation [J]. Surface & Coatings Technology, 2006, 200 (11): 3486-3491.
[95] H. Wang, R. Akid. Encapsulated Cerium Nitrate Inhibitors to Provide High-Performance Anti-Corrosion Sol-Gel Coatings on Mild Steel [J]. Corrosion Science, 2008, 50 (4): 1142-1148.
[96] Y.A. Chen, C.C. Wu, X.G. Ding, et al. Effect of of Water Amount and Teos/Mtes Ratio on Anti-Corrosion Property of Organic-Inorganic Film [J]. Rare Metal Materials and Engineering, 2010, 39: 288-291.
[97] M.G. Olivier, M. Fedel, V. Sciamanna, et al. Study of the Effect of Nanoclay Incorporation on the Rheological Properties and Corrosion Protection by a Silane Layer [J]. Progress in Organic Coatings, 2011, 72 (1-2): 15-20.
[98] A. Conde, J. De Damborenea, A. Duran, et al. Protective Properties of a Sol-Gel Coating on Zinc Coated Steel [J]. Journal of Sol-Gel Science and Technology, 2006, 37 (1): 79-85.
[99] T.P. Chou, C. Chandrasekaran, S. Limmer, et al. Organic-Inorganic Sol-Gel Coating for Corrosion Protection of Stainless Steel [J]. Journal of Materials Science Letters, 2002, 21 (3): 251-255.
[100] T.P. Chou, C. Chandrasekaran, G.Z. Cao. Sol-Gel-Derived Hybrid Coatings for Corrosion Protection [J]. Journal of Sol-Gel Science and Technology, 2003, 26 (1-3): 321-327.
[101] S. Cere, A. Pepe, M. Aparicio, et al. Cerium Hybrid Silica Coatings on Stainless Steel Aisi 304 Substrate [J]. Journal of Sol-Gel Science and Technology, 2006, 39 (2): 131-138.
[102] R. Okner, A.J. Domb, D. Mandler. Electrochemically Deposited Poly(Ethylene Glycol)-Based Sol-Gel Thin Films on Stainless Steel Stents [J]. New Journal of Chemistry, 2009, 33 (7): 1596-1604.
[103] J. Ballarre, D.A. Lopez, A.L. Cavalieri. Nano-Indentation of Hybrid Silica Coatings on Surgical Grade Stainless Steel [J]. Thin Solid Films, 2008, 516 (6): 1082-1087.
[104] S.M. Hosseinalipour, A. Ershad-Langroudi, A.N. Hayati, et al. Characterization of Sol-Gel Coated 316l Stainless Steel for Biomedical Applications [J]. Progress in Organic Coatings, 2010, 67 (4): 371-374.
[105] V.H.V. Sarmento, M.G. Schiavetto, P. Hammer, et al. Corrosion Protection of Stainless Steel by Polysiloxane Hybrid Coatings Prepared Using the Sol-Gel Process [J]. Surface & Coatings Technology, 2010, 204 (16-17): 2689-2701.
[106] D.A. Lopez, N.C. Rosero-Navarro, J. Ballarre, et al. Multilayer Silica-Methacrylate Hybrid Coatings Prepared by Sol-Gel on Stainless Steel 316l: Electrochemical Evaluation [J]. Surface & Coatings Technology, 2008, 202 (10): 2194-2201.
[107] J. Ballarre, D.A. Lopez, N.C. Rosero, et al. Electrochemical Evaluation of Multilayer Silica-Metacrylate Hybrid Sol-Gel Coatings Containing Bioactive Particles on Surgical Grade Stainless Steel [J]. Surface & Coatings Technology, 2008, 203 (1-2): 80-86.
[108] M. Ghaffari, A. Barzegar, K. Janghorban, et al. Investigation of Effective Parameters in Improving Corrosion Resistance of Silica Coated Stainless Steel Via Sol-Gel Method [J]. Corrosion Engineering Science and Technology, 2011, 46 (5): 605-610.
[109] J. Gallardo, A. Duran, I. Garcia, et al. Effect of Sintering Temperature on the Corrosion and Wear Behavior of Protective Sio2-Based Sol-Gel Coatings [J]. Journal of Sol-Gel Science and Technology, 2003, 27 (2): 175-183.
[110] Y.Q. Yang, L. Liu, J.M. Hu, et al. Improved Barrier Performance of Metal Alkoxide-Modified Methyltrimethoxysilane Films [J]. Thin Solid Films, 2012, 520 (6): 2052-2059.
[111] E. Bescher, J.D. Mackenzie. Sol-Gel Coatings for the Protection of Brass and Bronze [J]. Journal of Sol-Gel Science and Technology, 2003, 26 (1-3): 1223-1226.
[112] A.J. Vreugdenhil, M.E. Woods. Continuously Responsive Epoxy-Amine Cross-Linked Silicon Sol-Gel Materials [J]. Journal of Materials Science, 2006, 41 (22): 7545-7554.
[113] S.S. Peng, W.J. Zhao, H. Li, et al. The Enhancement of Benzotriazole on Epoxy Functionalized Silica Sol-Gel Coating for Copper Protection [J]. Applied Surface Science, 2013, 276: 284-290.
[114] S.V. Lamaka, M.F. Montemor, A.F. Galio, et al. Novel Hybrid Sol-Gel Coatings for Corrosion Protection of Az31b Magnesium Alloy [J]. Electrochimica Acta, 2008, 53 (14): 4773-4783.
[115] A.F. Galio, S.V. Lamaka, M.L. Zheludkevich, et al. Inhibitor-Doped Sol-Gel Coatings for Corrosion Protection of Magnesium Alloy Az31 [J]. Surface & Coatings Technology, 2010, 204 (9-10): 1479-1486.
[116] X.H. Guo, M.Z. An. Experimental Study of Electrochemical Corrosion Behaviour of Bilayer on Az31b Mg Alloy [J]. Corrosion Science, 2010, 52 (12): 4017-4027.
[117] H.M. Wang, R. Akid, M. Gobara. Scratch-Resistant Anticorrosion Sol-Gel Coating for the Protection of Az31 Magnesium Alloy Via a Low Temperature Sol-Gel Route [J]. Corrosion Science, 2010, 52 (8): 2565-2570.
[118] J.Y. Hu, Q. Li, X.K. Zhong, et al. Organic Coatings Silane-Based for Az91d Magnesium Alloy [J]. Thin Solid Films, 2010, 519 (4): 1361-1366.
[119] J.Y. Hu, Q. Li, X.K. Zhong, et al. Fluoride Treatment and Sol Film Composite Technology for Az91d Magnesium Alloy [J]. Transactions of the Institute of Metal Finishing, 2010, 88 (1): 41-46.
[120] H.W. Shi, F.C. Liu, E.H. Han. Corrosion Protection of Az91d Magnesium Alloy with Sol-Gel Coating Containing 2-Methyl Piperidine [J]. Progress in Organic Coatings, 2009, 66 (3): 183-191.
[121] B. Nikrooz, M. Zandrahimi. Optimization of Process Variables and Corrosion Properties of a Multi Layer Silica Sol Gel Coating on Az91d Using the Box-Behnken Design [J]. Journal of Sol-Gel Science and Technology, 2011, 59 (3): 640-649.
[122] Y. Tamar, D. Mandler. Corrosion Inhibition of Magnesium by Combined Zirconia Silica Sol-Gel Films [J]. Electrochimica Acta, 2008, 53 (16): 5118-5127.
[123] J. Hu, Q. Li, X. Zhong, et al. Novel Anti-Corrosion Silicon Dioxide Coating Prepared by Sol-Gel Method for Az91d Magnesium Alloy [J]. Progress in Organic Coatings, 2008, 63 (1): 13-17.

备注/Memo

备注/Memo:
基金项目:国家自然科学基金资助项目(59493300);教育部博士点基金资助项目(9800462)
更新日期/Last Update: 2014-01-02