[1]黄燕,李鼎,孟竹,等.共价有机聚合物的合成及在燃料电池阴极氧还原反应中的应用[J].中国材料进展,2017,(7-8):041-45.[doi:10.7502/j.issn.1674-3962.2017.07.05]
　HUANG Yan,LI Ding,MENG Zhu,et al.Synthesis and Application of Covalent Organic Polymers in Oxygen Reduction Reaction for Fuel Cell[J].MATERIALS CHINA,2017,(7-8):041-45.[doi:10.7502/j.issn.1674-3962.2017.07.05]
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共价有机聚合物的合成及在燃料电池阴极氧还原反应中的应用()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
期数:
2017年第7-8期
页码:
041-45
栏目:
前沿综述
出版日期:
2017-08-31

文章信息/Info

Title:
Synthesis and Application of Covalent Organic Polymers in Oxygen Reduction Reaction for Fuel Cell
作者:
黄燕; 李鼎; 孟竹; 周卓航; 郭佳宁; 程元徽; 向中华
北京化工大学分子能源材料研发中心，有机无机复合材料国家重点实验室
Author(s):
HUANG Yan;  LI Ding;  MENG Zhu;  ZHOU Zhuohang;  GUO Jianing; CHENG Yuanhui;  XIANG Zhonghua
State Key Laboratory of OrganicInorganic Composites， Molecular Energy Materials R&D Center， Beijing University of Chemical Technology，
关键词:
共价有机聚合物; 电催化; 氧还原反应; 燃料电池; 多孔聚合物
Keywords:
covalent organic polymers;  electrocatalysts;  oxygen reduction reaction;  fuel cell;  porous polymers
DOI:
10.7502/j.issn.1674-3962.2017.07.05
文献标志码:
A
摘要:
共价有机聚合物（Covalent Organic Polymers， COPs）是一类通过共价键将不同几何构型和长度的有机配体组装成多维度多功能的高水热稳定性的有机多孔材料，具有高比表面积、孔道尺寸可控及结构多样的特性，在能源的转化和储存领域应用前景广阔。围绕COP材料在燃料电池阴极氧还原催化领域中的应用，重点总结了二维、三维及功能化COP材料的合成策略与方法，及几类代表性前驱体（卟啉类、三嗪类、聚苯胺类以及复合类）在氧还原电催化中的调控与性能研究。COP材料的定向裁剪和功能化，可为高效氧还原催化材料的制备提供便捷、丰富、可控的新型合成平台，推动燃料电池新型催化剂的研发，为突破燃料电池工业应用提供新方案。
Abstract:
Covalent organic polymers (COPs) are a class of multidimensional， multifunctional and high hydrothermal stable organic porous materials， which are built via covalent bond of colorful organic building blocks. The high specific surface area， inherent optimized pore size and diverse structure contribute to its promising applications in the field of energy conversion and storage. In this review， we briefly summarize recent progress on efficient electrocatalysts for oxygen reduction reaction(ORR) basing on COPs in the fuel cell. First， we summarize the synthesis strategies of twodimensional， threedimensional and functional COPs， and subsequently review the ORR performance of COP materials according to four types of representative precursors， i.e.， porphyrins， triazines， polyanilines and hybrids. Due to tunable structural characteristics and multichemical functionality， COP materials can offer convenient， abundant and controllable new synthetic platform for preparation of efficient ORR electrocatalysts， promote research of new fuel cell catalyst， and provide new solutions for breakthrough of fuel cell for industrial applications.
更新日期/Last Update: 2017-09-07