[1]黄辉,黄亨建.后CHNO类含能材料的发展思考[J].中国材料进展,2018,(11):016-20.[doi:10.7502/j.issn.1674-3962.2018.11.06]
 Huang Hui,Huang Heng-jian.Insights into the Development for Post-CHNO Energetic Materials[J].MATERIALS CHINA,2018,(11):016-20.[doi:10.7502/j.issn.1674-3962.2018.11.06]
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后CHNO类含能材料的发展思考()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
期数:
2018年第11期
页码:
016-20
栏目:
特约研究论文
出版日期:
2018-11-30

文章信息/Info

Title:
Insights into the Development for Post-CHNO Energetic Materials
作者:
黄辉1 黄亨建2
1.中国工程物理研究院,四川 绵阳 621900;2. 中国工程物理研究院化工材料研究所,四川 绵阳 621900
Author(s):
Huang Hui1 Huang Heng-jian2
1.China Academy of Engnieering Physics (CAEP); 2. Institute of Chemical Materials (ICM), China Academy of Engnieering Physics (CAEP)
关键词:
含能材料CHNO类高能量密度贮能设计
Keywords:
energetic materialsCHNOHEDMenergy storage design
DOI:
10.7502/j.issn.1674-3962.2018.11.06
文献标志码:
A
摘要:
现代武器装备对含能材料提出了更高要求,传统含能材料的发展遇到新挑战。本文分析了传统CHNO类含能材料存在能量与感度及稳定性陷阱、贮能释能已接近极限等技术瓶颈。综述了国内外笼形化合物、氮簇化合物及聚合氮、金属氢等方面的新进展和研究动向。提出了基于炸药爆炸行为与反应速率调控新技术,运用多尺度设计理论和方法,拓展含能分子贮能体系的新思路,主要包括基于原子组合的化学键贮能设计、基于分子组合的分子间贮能设计、 基于微纳米结构复合的贮能设计等途径,探讨未来高能量密度含能材料(HEDM)的发展思路。关键词:
Abstract:
Modern warfare puts forward new requirements for weapon equipments, such as long-distance delivery, precision strike, high-efficiency damage and strong survivability, hence traditional energetic materials face unprecedented challenges. This paper reviewed the main bottlenecks in the development of CHNO energetic materials, energy and sensitivity, stability contradictions, and energy storage-release limit. The research and development trends in cage compounds, nitrogen compounds, and polymeric nitrogen, and metal hydrogen at home and abroad were briefly introduced. Based on these ideas, new strategies were proposed to design energetic materials by multi-scale methods, and further expand the molecular energy storage system according to the explosion features of explosives and the control of reaction rate. Some potential design approchs to energy storage based on atomic combination, molecular combination and micro/nano-structure composites are recommended to carry out extensive and profound researchs in energetic material fields.
更新日期/Last Update: 2018-11-02