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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

Title:: Research Progress in Preparation and Applications of Conjugated Microporous Polymers

Author(s):: HU Xiaowen; WANG Haige; HE Yan; LI Huixin; LI Huimin; CHENG Zhonghua; LIAO Yaozu; State Key Laboratory for Modification of Fibers and Polymer Materials，College of Material Science and Engineering，Donghua University

Keywords:: conjugated microporous polymer; organic porous materials; preparation; gas adsorption; chemical sensing; catalysis; energy storage and conversion

摘要:: 共轭微孔聚合物是一类由全共轭分子链构筑，具有三维网络骨架、自具微孔结构且孔径小于2 nm的有机多孔材料。从分子结构上看，共轭单元的刚性和成键方式导致其骨架能有效地支撑起微孔通道，而不像共轭小分子或线性共轭聚合物那样通过ππ堆积形成致密的凝聚体。因此，共轭微孔聚合物既拥有某些共轭聚合物的光电性质，又能够提供稳定的多孔性；同时，还具有功能调控、环境稳定性高、制备路径简单和多元化等特点。自2007年首次制备获得共轭微孔聚合物以来，至今为止已经发展了多种制备方法，并且在气体吸附、化学传感、异相催化、能量存储与转换等诸多领域取得了重要应用。系统归纳了共轭微孔聚合物的制备方法和应用，同时总结了共轭微孔聚合物研究目前存在的主要问题以及未来发展方向。

Abstract:: Conjugated microporous polymers (CMPs) are a class of porous organic polymers, which consist of fully conjugated molecular chains with a threedimensional network skeleton and have a microporous structure with a pore diameter of less than 2 nm. From the molecular structure, the rigidity and bonding mode of the conjugated units render its skeleton to effectively support the microporous channel, instead of forming a ππ stacking like those dense agglomerates as found in conjugated small molecules, linear conjugated polymers. Therefore, CMPs not only possess the photoelectric properties of certain conjugated polymers, but also provide stable porosity, and have the characteristics of functional cutting, high environmental stability, simple preparation pathway and diversification. Since the first preparation of CMPs in 2007, various preparation methods have been developed so far, and a series of applications have been achieved in the fields of gas adsorption, chemical sensing, heterogeneous catalysis, energy storage and conversion. In this review, the preparation methods and applications of conjugated microporous polymers are summarized, and the main problems and future development directions of CMPs are summarized.

备注/Memo:: 廖耀祖：男，1982年生，东华大学材料科学与工程学院、纤维材料改性国家重点实验室研究员/博士生导师、课题组组长。先后在美国加州大学洛杉矶分校、英国布里斯托大学、德国柏林工业大学学习工作6年时间。入选上海市浦江人才计划、德国洪堡学者以及欧洲玛丽居里学者奖励计划，并获得英国文化交流协会牛顿基金旅行资助等。主要从事共轭有机多孔材料的精准制备及其传感检测、吸附分离、清洁能源开发等基础应用研究。拥有美国、欧洲、中国发明专利18件。在Adv Mater(1篇)、ACS Macro Lett(1篇)、Macromolecules(3篇)、Chem Sci(3篇)、Chem Mater(1篇)、Small(1篇)、MaterHoriz (1篇)、Adv Funct Mater(1篇)、Nano Lett(1篇)、ACS Nano(1篇)等国际重要期刊发表SCI论文50余篇，其中IF>9的论文11篇，封面/扉页论文4篇，ESI高被引论文5篇。截止2019年4月，论文已被引用近1700次。研究成果被人民网、中国科学报、美国化学会Noteworthy Chemistry、德国Thieme Synfacts、英国皇家化学会Chemistry World、欧洲ChemEurope等30余家媒体跟踪报道。先后主持国家自然科学基金（3项）、上海市自然科学基金（2项）等国家级、省部级和国际合作项目14项。

更新日期/Last Update: 2019-04-01