[1]沈岳松,祝社民,沈晓冬.选择性催化还原脱硝催化材料研究进展[J].中国材料进展,2019,(12):1125-1134.[doi:10.7502/j.issn.16743962.201904024]
　SHEN Yuesong,ZHU Shemin,SHEN Xiaodong.Research Progress on Catalytic Materials for Selective Catalytic Reduction of Nitrogen Oxides[J].MATERIALS CHINA,2019,(12):1125-1134.[doi:10.7502/j.issn.16743962.201904024]
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选择性催化还原脱硝催化材料研究进展()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
期数:
2019年第12期
页码:
1125-1134
栏目:
前沿综述
出版日期:
2019-12-31

文章信息/Info

Title:
Research Progress on Catalytic Materials for Selective Catalytic Reduction of Nitrogen Oxides
文章编号:
16743962(2019)12112510
作者:
沈岳松; 祝社民; 沈晓冬
(南京工业大学材料科学与工程学院，江苏 南京 211816）
Author(s):
SHEN Yuesong;  ZHU Shemin;  SHEN Xiaodong
(College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China)
关键词:
脱硝; 选择性催化还原; 钒基脱硝催化剂; 稀土基脱硝催化剂; 铈基复合氧化物; 船舶脱硝; 脱硝新挑战
Keywords:
deNOx;  selective catalytic reduction;  vanadiumbased deNOx catalyst;  rare earthbased deNOx catalyst;  ceriumbased complex oxides;  ship deNOx;  deNOx new challenge
分类号:
TQ426
DOI:
10.7502/j.issn.16743962.201904024
文献标志码:
A
摘要:
氮氧化物（NOx）是大气污染长久治理的重点，工业主流氨气选择性催化还原NOx的技术核心是脱硝催化剂，研发环境友好型高效脱硝催化剂是世界环保的共同需求。简述了脱硝需求背景、脱硝催化剂应用现状及现存问题，概述了贵金属、金属氧化物及离子交换型分子筛3大类脱硝催化剂的研究进展；重点论述了环境友好型稀土基脱硝催化剂的研发历程，以及船用无毒选择性催化还原（SCR）脱硝催化剂的研究进展。我国自主研发的稀土基脱硝催化剂是第二种实现规模化工业应用的烟气脱硝催化剂，被国家三部委指定为钒基催化剂的替代产品，成为未来工业脱硝应用的重点新材料。从行业NOx超低排放驱动及恶劣工况脱硝难度两方面，探讨了脱硝催化剂面临的新挑战，指出抗水硫中毒能力强的超低温催化剂、耐水热稳定性强的高温催化剂及脱硝催化剂多功能化治理其他污染物，是今后脱硝催化剂发展的重点。
Abstract:
Nitrogen oxides (NOx) are the long-term focus of air pollution control, the technological core of industrial mainstream selective catalytic reduction of NOx with ammonia is deNOx catalyst, and the research and development of environmentally friendly and highly efficient deNOx catalysts is a common requirement of the world’s environmental protection. The background of deNOx demand, the application status of deNOx catalysts and existing problems are briefly described, and the research progress of three types of deNOx catalysts, including noble metals, metal oxides and ion-exchanged zeolites are summarized. The development progress of the environmentally friendly rare earth-based deNOx catalysts and the research progress on non-toxic SCR catalysts for marine deNOx are highlighted. The rare earth-based deNOx catalyst independently developed by China is the second flue gas deNOx catalyst for large-scale industrial application, which has been designated as a substitute for the vanadium-based catalyst by the three state ministries and the national development and reform commission, and will become a key material for industrial deNOx applications in the future. From the two aspects of ultra-low NOx emission demand driven by different industries and the difficulty of deNOx in severe working conditions, the new challenges of deNOx catalysts are discussed. The ultra-low temperature deNOx catalysts with strong anti-water and sulfur dioxide poisoning abilities, the high temperature deNOx catalysts with high hydrothermal stability, and the new multifunctionalization of deNOx catalysts for treating other pollutants, are the focuses of future development.

备注/Memo

备注/Memo:
收稿日期：20190424修回日期：20191213 基金项目：国家重点研发计划项目（2016YFC0205500）；国家自然科学基金资助项目（51772149）；江苏省“六大人才高峰”项目（JNHB044）；江苏高校‘青蓝工程’资助项目第一作者：沈岳松，男，1981年生，研究员，硕士生导师， Email:shenyuesong@njtech.edu.cn
更新日期/Last Update: 2019-11-29