玻璃表面功能化改性技术的现状与发展-中国材料进展

文章信息/Info

Title:: Current Status and Development of Functional Modification Technology of Glass Surface

Author(s):: WANG Haobo; LI Chuanqiang; (School of Materials Science and Engineering, Chongqing Jiaotong University, Chongqing 400074, China)

Keywords:: glass; surface modification; composite properties; modification mechanism; functionalization

摘要:: 玻璃表面功能化改性是制备功能玻璃、拓展玻璃应用领域的重要方法与有效途径。通过高能粒子法、偶联剂改性法、化学接枝法、交联改性法等改性技术在玻璃表面沉积、喷涂、镀膜,可在玻璃基本性能的基础上赋予其良好的蓄光发光、超导、信息存储、抗菌自清洁、金属化、光催化、抗静电等复合性能。主要综述了玻璃表面改性方法的研究进展,讨论了溅射沉积法、热喷涂法、化学气相沉积法、溶胶凝胶法等传统工艺成本低廉、界面功能化程度低、改性界面性能差等特点,并分析概括了高能粒子法、偶联作用、化学接枝、交联改性等新型改性技术的作用机理及研究进展。

Abstract:: Functionalization of glass surface is an important method and effective way to prepare functional glass and expand its application fields. By depositing, coating and plating on the glass surface through high-energy particle action, coupling grafting and chemical cross-linking, the glass can be endowed with good composite properties such as light storage and luminescence, superconductivity, information storage, antibacterial self-cleaning, metallization, photocatalysis and antistatic properties on top of its basic properties. This paper mainly reviews the research progress of glass surface modification methods, discusses the characteristics of traditional processes including sputtering deposition, thermal spraying, chemical vapor deposition, sol-gel method, etc. These methods have advantages of low cost, but also have problems of low level of interface functionalization and poor performance of modified interfaces, and analyzes and outlines the mechanism and research progress of new modification techniques such as high-energy particle method, coupling, chemical grafting and cross-linking modification.