[1]任杨斌,范燕平,刘宪云,等.镍基催化剂催化氨硼烷水解产氢研究进展[J].中国材料进展,2022,41(04):288-295.[doi:10.7502/j.issn.1674-3962.202105009]
 REN Yangbin,FAN Yanping,LIU Xianyun,et al.Research Progress on Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane over Ni Catalysts[J].MATERIALS CHINA,2022,41(04):288-295.[doi:10.7502/j.issn.1674-3962.202105009]
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镍基催化剂催化氨硼烷水解产氢研究进展()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
41
期数:
2022年第04期
页码:
288-295
栏目:
前沿综述
出版日期:
2022-04-30

文章信息/Info

Title:
Research Progress on Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane over Ni Catalysts
文章编号:
1674-3962(2022)04-0288-08
作者:
任杨斌范燕平刘宪云段继转刘宝忠
(河南理工大学化学化工学院,河南 焦作 454003)
Author(s):
REN Yangbin FAN Yanping LIU Xianyun DUAN Jizhuan LIU Baozhong
School of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454003, China
关键词:
氨硼烷产氢水解催化
Keywords:
ammonia borane hydrogen production hydrolysis Ni catalyst
分类号:
TQ426.8
DOI:
10.7502/j.issn.1674-3962.202105009
文献标志码:
A
摘要:
氢气作为一种清洁能源,被认为是化石能源最理想的替代者。安全、高效且稳定的储氢材料的开发是当前氢能源应用研究中面临的最大挑战之一。氨硼烷(NH3BH3,AB)因其较高的储氢密度(146 g·L-1,质量分数为19.6%)、安全无毒及高化学稳定性等特性成为一种重要的化学固态储氢材料。氨硼烷水解制氢反应条件温和,但需要在合适的催化剂存在的条件下进行。通过调节催化剂的活性组分、颗粒尺寸、活性组分的分散度、电子结构等,可显著提高氨硼烷水解产氢速率。综述了近年来氨硼烷水解制氢反应中镍基催化剂的研究进展,重点概述了镍单质、镍化合物以及镍合金催化剂在氨硼烷水解产氢中的应用,阐述了氨硼烷水解产氢反应机理,展望了氨硼烷水解产氢的发展趋势以及面临的挑战。
Abstract:
Hydrogen, as clean energy, has been considered as a promising alternative to the fossil fuel. The development of safe, efficient and stable hydrogen storage materials is one of the biggest challenges in the current hydrogen energy research. Ammonia borane has become an important chemical solid-state hydrogen storage material due to its high hydrogen storage capacity (146 g·L-1, mass fraction is 19.6%), safety, non-toxicity and high chemical stability. Hydrogen generation by hydrolysis of ammonia borane can be carried out under the mild conditions with the presence of suitable catalyst. The hydrogen production rate of ammonia borane hydrolysis can be significantly improved by adjusting the active components, particle size, dispersion degree of active component, electronic structure, et al. This paper reviews the research progress of Ni-based catalysts in the hydrolysis of ammonia borane for hydrogen production in recent years. The application of nickel elementals, nickel compounds and nickel alloy catalysts for ammonia borane hydrolysis is mainly summarized. Meanwhile, the reaction mechanism of ammonia borane hydrolysis for hydrogen production is described. The development trend and the potential challenges of hydrogen production from ammonia borane hydrolysis are prospected.

备注/Memo

备注/Memo:
收稿日期:2021-05-11? ?修回日期:2021-07-06
基金项目:国家自然科学基金项目(U1804135,52071135,51871090,51671080,21805071);中原科技创新领军人才项目(194200510019);河南省高等学校重点科研项目(19A150025);河南省自然科学基金项目(202300410174);河南省高校基本科研业务费专项资金项目(NSFRF180307);河南省煤炭绿色转化重点实验室研究基金项目(CGCF201808)
第一作者:任杨斌,男,1988年生,博士研究生
通讯作者:刘宝忠,男,1976年生,教授,博士生导师,Email:bzliu@hpu.edu.cn
更新日期/Last Update: 2022-03-29