[1]徐小鹏,彭强.金属络合物在有机太阳能电池中的应用研究进展[J].中国材料进展,2022,41(03):178-187.[doi:10.7502/j.issn.1674-3962.202112017]
　XU Xiaopeng,PENG Qiang.Recent Advances of Metal Complexes for Organic Solar Cells[J].MATERIALS CHINA,2022,41(03):178-187.[doi:10.7502/j.issn.1674-3962.202112017]
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金属络合物在有机太阳能电池中的应用研究进展()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
41
期数:
2022年第03期
页码:
178-187
栏目:
出版日期:
2022-03-30

文章信息/Info

Title:
Recent Advances of Metal Complexes for Organic Solar Cells
文章编号:
1674-3962(2022)03-0178-10
作者:
徐小鹏1; 彭强1; 2
（1. 四川大学化学工程学院，四川 成都 610065）（2. 四川大学 高分子材料工程国家重点实验室，四川 成都 610065）
Author(s):
XU Xiaopeng1;  PENG Qiang1; 2
（1.School of Chemical Engineering，Sichuan University，Chengdu 610065，China) （2.State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China）
关键词:
有机太阳能电池; 金属络合物; 给体材料; 受体材料; 添加剂; 界面材料
Keywords:
organic solar cells;  metal complex;  donor materials;  acceptor materials;  additives;  interfacial materials
分类号:
O626;TM914.4
DOI:
10.7502/j.issn.1674-3962.202112017
文献标志码:
A
摘要:
全球性的环境与能源危机已成为可持续发展必须面临的重要问题，开发清洁可再生能源以替代传统化石能源成为当今社会关注的焦点之一。其中，利用太阳能电池将太阳能转化为电能是清洁可再生能源领域最有前景的解决方案。在众多太阳能电池技术中，有机太阳能电池因具有质量轻、原材料来源广泛、成本低、机械柔性好、可采用湿法制备成大面积器件等优势而备受关注。开发高性能的电子给、受体材料以及界面材料是进一步提升有机太阳能电池光电转换效率的关键。其中，金属络合物因其较高的三线态激子密度、较长的激子寿命以及较高的荧光量子产率而引起广泛的研究兴趣。近年来，金属络合物材料越来越多地被用在有机太阳能电池中，并使器件获得了较高的性能。从金属络合物的给体材料、受体材料、添加剂以及界面材料4个方面对金属络合物材料在有机太阳能电池中的应用做简要介绍，探讨这些金属络合物“结构-性质”之间的关系，并对其未来在有机太阳能电池应用方面的发展进行展望。
Abstract:
Global environment and energy crises have become the severe obstacles to socio-economic development and survival environment of mankind. The development of clean renewable energy to replace traditional fossil fuels has become one of the main focuses of today’s society. Converting solar energy into electricity by solar cells represents one of the most promising ways. Among the various solar cell techniques, organic solar cells have attracted much attention for their advantages in light weight, wide range, low cost of raw material sources, good mechanical flexibility, and easy wet-processing for large-area devices. The key to further improve the power conversion efficiency of organic solar cells is developing high-performance electron donor and acceptor materials as well as interfacial materials. Among the organic semiconductors, metal complexes have received considerable research interests owing to their high triplet populations, long exciton lifetimes and high fluorescence quantum yield. In recent years, more and more metal complex-based organic semiconductors have been applied in the field of organic solar cells and obtained high device performances. This review briefly introduces the recent applications of metal complexes in organic solar cells from four aspects of electron donors, electron acceptors, additives and interfacial materials. The “structure-property” relationship of the metal complexes is discussed, and their futural development is also prospected.

备注/Memo

备注/Memo:
收稿日期：2021-12-22 修回日期：2022-01-21 基金项目：国家自然科学基金资助项目（21825502, 22075190, 22105135）第一作者：徐小鹏，男，1989年生，研究员，博士生导师, Email:xpxu@scu.edu.cn 通讯作者：彭强，男，1975年生，教授，博士生导师， Email:qiangpeng@scu.edu.cn
更新日期/Last Update: 2022-02-25