[1]武文俊.可印刷介观钙钛矿太阳能电池研究进展[J].中国材料进展,2026,45(07):569-581.[doi:10.7502/j.issn.1674-3962.202603006]
　Wenjun Wu.Recent Advances in Printable Mesoscopic Perovskite Solar Cells[J].MATERIALS CHINA,2026,45(07):569-581.[doi:10.7502/j.issn.1674-3962.202603006]
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可印刷介观钙钛矿太阳能电池研究进展()

中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
45
期数:
2026年07
页码:
569-581
栏目:
出版日期:
2026-06-30

文章信息/Info

Title:
Recent Advances in Printable Mesoscopic Perovskite Solar Cells
文章编号:
1674-3962(2026)07-0569-13
作者:
武文俊
华东理工大学化学与分子工程学院 精细化工研究所，上海 200237
Author(s):
Wenjun Wu
Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
关键词:
钙钛矿太阳能电池; 可印刷介观结构; 碳电极; 三层介孔支架; 界面工程; 缺陷钝化; 器件稳定性
Keywords:
perovskite solar cells;  printable mesoscopic architecture;  carbon electrodes; triple-layer mesoporous scaffold;  interface engineering;  defect passivation; device stability
分类号:
TM914.4; TB34
DOI:
10.7502/j.issn.1674-3962.202603006
文献标志码:
A
摘要:
金属卤化物钙钛矿材料因其高吸收系数、长载流子扩散长度以及低成本溶液加工特性，在光伏领域展现出巨大应用潜力，推动了钙钛矿太阳能电池在过去10余年中的快速发展。其中，采用TiO2/ZrO2/碳三层介孔支架结构的可印刷介观钙钛矿太阳能电池由于无需空穴传输材料和贵金属电极，并可通过丝网印刷实现全湿法制备，展现出优异的稳定性和规模化制造潜力。近年来，通过多阳离子组分工程、界面缺陷钝化以及电子注入调控等策略，可印刷介观钙钛矿太阳能电池的光电转换效率已突破23%，并在高温及长期运行条件下表现出优异的稳定性。系统综述了可印刷介观钙钛矿太阳能电池的研究进展，重点介绍其典型三层介孔结构及无空穴传输材料器件的电荷传输机制，阐述钙钛矿在多孔网络中的渗透填充与受限结晶行为，并总结半导体氧化物支架、碳对电极及钙钛矿吸光层等关键材料的优化策略及其对器件性能的影响机制。最后，针对钙钛矿填充均匀性不足、界面电荷易复合以及大面积印刷一致性不足等关键问题进行讨论，并展望通过界面工程、晶界精准钝化及规模化印刷工艺优化等途径进一步提升器件效率与稳定性的研究方向。
Abstract:
Metal halide perovskite solar cells have emerged as one of the most promising photovoltaic technologies owing to their high absorption coefficient, long carrier diffusion length and low-cost solution processability. Among the various device architectures, printable mesoscopic perovskite solar cells (p-MPSCs) employing a TiO2/ZrO2/carbon triple-layer mesoporous scaffold have attracted significant attention. By eliminating the need for hole transport materials and noble metal electrodes, and enabling fully wet fabrication via screen-printing techniques, p-MPSCs exhibit remarkable operational stability and strong potential for scalable manufacturing. In recent years, continuous progress in composition engineering, interfacial defect passivation and charge transport regulation has boosted the power conversion efficiency of p-MPSCs to over 23%, accompanied by excellent thermal and long-term operational stability. This review provides a comprehensive overview of recent advances in pMPSCs. The device architecture and charge transport mechanism of holetransport-material-free mesoscopic structures are first discussed. Particular emphasis is placed on the infiltration and confined crystallization behavior of perovskites within mesoporous networks. In addition, recent progress in optimizing key components, including semiconductor oxide scaffolds, carbon counter electrodes and perovskite absorber layers, is summarized, together with their impacts on device performance. Finally, key challenges are discussed, including non-uniform perovskite deposition, interfacial charge recombination and poor large-area printing consistency, followed by an outlook on improving device efficiency and stability via interface engineering, grain boundary passivation and scalable printing process optimization.

备注/Memo

备注/Memo:
收稿日期：2026-03-08修回日期：2026-05-13 基金项目：国家自然科学基金资助项目（22478115）；广西科技创新平台计划项目（桂科LT2504240035） 作者简介：武文俊，男，1976年生，教授，博士生导师， Email: wjwu@ecust.edu.cn
更新日期/Last Update: 2026-06-02