[1]袁景阳,吴义炳,高照昆,等.工艺与材料协同：大面积钙钛矿光伏器件的挑战与对策[J].中国材料进展,2026,45(07):606-621.[doi:10.7502/j.issn.1674-3962.202603012]
　YUAN Jingyang,WU Yibing,GAO Zhaokun,et al.Process-Material Synergy in Large-Area Perovskite Photovoltaic Device: Challenges and Solutions[J].MATERIALS CHINA,2026,45(07):606-621.[doi:10.7502/j.issn.1674-3962.202603012]
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工艺与材料协同：大面积钙钛矿光伏器件的挑战与对策()

中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
45
期数:
2026年07
页码:
606-621
栏目:
出版日期:
2026-06-30

文章信息/Info

Title:
Process-Material Synergy in Large-Area Perovskite Photovoltaic Device: Challenges and Solutions
文章编号:
1674-3962(2026)07-0606-16
作者:
袁景阳; 吴义炳; 高照昆; 蔡庆斌; 欧阳新华
福建农林大学光电产业学院，福建 泉州 362406
Author(s):
YUAN Jingyang;  WU Yibing;  GAO Zhaokun;  CAI Qingbin;  OUYANG Xinhua
College of Optoelectronic Industry, Fujian Agriculture and Forestry University, Quanzhou 362406, China
关键词:
钙钛矿太阳能电池; 大面积制备; 功能添加剂; 界面工程; 电荷传输层; 稳定性; 产业化
Keywords:
perovskite solar cells;  largearea fabrication;  functional additives;  interface engineering;  charge transport layers;  stability;  industrialization
分类号:
TM914.4
DOI:
10.7502/j.issn.1674-3962.202603012
文献标志码:
A
摘要:
钙钛矿太阳能电池（PSCs）因其卓越的光电转换效率、低廉的制备成本以及可溶液加工特性，已成为下一代光伏技术的重要候选体系。近年来，实验室尺度小面积PSCs的光电转换效率已由38%迅速攀升至273%，展现出巨大的应用前景。然而，在从实验室小面积器件向产业化大面积模块的过渡过程中，仍面临薄膜均匀性下降、缺陷密度升高、界面复合加剧以及器件长期稳定性衰减等一系列核心瓶颈。单纯依靠沉积工艺的优化已难以满足高性能大面积器件的制备需求，关键在于开发新型功能材料，以期从分子层面调控结晶动力学、钝化缺陷态、优化能级匹配结构，并有效抑制离子迁移行为。首先，系统剖析了大面积制备过程中的主要科学挑战，并简要介绍了刮涂、狭缝涂布、喷墨打印及气相沉积等大面积制备技术的工艺特点与适用性；随后，重点阐述了功能添加剂、界面钝化分子以及新型电荷传输层材料在构筑高质量大面积钙钛矿薄膜中的关键作用，系统讨论了组分调控工程、界面工程与传输层优化策略在协同提升器件性能与稳定性方面的研究进展；最后，结合产业化发展需求，展望了未来高效稳定、环境友好的功能材料体系的设计思路与发展方向，以期为推动PSCs的商业化应用提供理论依据与技术参考。
Abstract:
Perovskite solar cells (PSCs) have emerged as a transformative candidate for nextgeneration photovoltaics, offering exceptional power conversion efficiency, lowcost fabrication and solution processability. In recent years,the power conversion efficiency of labscale and smallarea PSCs has surged from 3.8% to 27.3%, underscoring their immense commercial potential.Nevertheless, the translation of these achievements to industrialscale and largearea modules remains constrained by critical challenges, including most notably, compromised film uniformity, heightened defect densities, aggravated interfacial recombination and inadequate longterm stability. While deposition process optimization has contributed to progress, it alone cannot meet the stringent demands of scalable manufacturing. A paradigm shift is required, centering on the rational design of novel functional materials that enable molecularlevel control over crystallization kinetics, defect passivation, energy level alignment and ion migration inhibition. This review begins by systematically outlining the key scientific issues in scaling up PSCs, followed by a concise overview of scalable deposition techniques, including blade coating, slot-die coating, inkjet printing, and vapor deposition with highlighting their respective merits and limitations. The core of the review then delves into the pivotal roles of functional additives, interfacial modifiers and advanced charge transport materials in realizing highquality and largearea perovskite films. We further discuss how compositions, interfaces and transport layer engineering strategies synergistically enhance both device performance and operational stability. To conclude, we offer a forwardlooking perspective on the design of nextgeneration material systems that balance efficiency, stability and environmental compatibility, aiming to provide a roadmap for the practical commercialization of PSCs technologies.

备注/Memo

备注/Memo:
收稿日期：2026-03-22修回日期：2026-05-15 基金项目：国家自然科学基金资助项目（22375043）；福建省科技重大专项（2025HZ028025）；福建省自然科学基金重点项目（2025J02013） 第一作者：袁景阳，男，2001年生，硕士研究生 通讯作者：欧阳新华，男，1980年生，教授，博士生导师， Email: ouyangxh@fafu.edu.cn 蔡庆斌，男，1991年，副教授，硕士生导师， Email: qingbinc@fafu.edu.cn
更新日期/Last Update: 2026-06-02