[1]王畅,施伟,杨娟,等.钙钛矿/硅叠层太阳能电池稳定性[J].中国材料进展,2026,45(07):584-605.[doi:10.7502/j.issn.1674-3962.202604010]
　WANG Chang,SHI Wei,YANG Juan,et al.Stability of Perovskite/Silicon Tandem Solar Cells[J].MATERIALS CHINA,2026,45(07):584-605.[doi:10.7502/j.issn.1674-3962.202604010]
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钙钛矿/硅叠层太阳能电池稳定性()

中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
45
期数:
2026年07
页码:
584-605
栏目:
出版日期:
2026-06-30

文章信息/Info

Title:
Stability of Perovskite/Silicon Tandem Solar Cells
文章编号:
1674-3962(2026)07-0584-22
作者:
王畅; 施伟; 杨娟; 杨新波
1. 苏州大学能源学院，江苏 苏州 215000 2. 江苏大学材料科学与工程学院，江苏 镇江 212000 3. 莫纳什大学苏州研究院，江苏 苏州 215000 4. 苏州实验室，江苏 苏州 215000
Author(s):
WANG Chang; SHI Wei; YANG Juan; YANG Xinbo
1. College of Energy, Soochow University, Suzhou 215000, China 2. School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212000, China 3. Monash Suzhou Research Institute, Monash University, Suzhou 215000, China 4. Suzhou Laboratory, Suzhou 215000, China
关键词:
钙钛矿/硅叠层太阳能电池; 稳定性; 界面工程; 器件封装; 稳定性测试
Keywords:
perovskite/silicon tandem solar cells;  stability;  interface engineering;  device encapsulation;  stability testing
分类号:
TM914.4
DOI:
10.7502/j.issn.1674-3962.202604010
文献标志码:
A
摘要:
近年来，钙钛矿/硅叠层太阳能电池因其能够突破单结光伏器件效率极限而成为光伏领域的研究热点。然而，相较于迅速提升的光电转换效率，器件稳定性不足问题仍是限制其规模化应用的关键因素。围绕钙钛矿/硅叠层太阳能电池稳定性不足的问题，对近年来相关研究进展进行了系统综述。首先分析了影响叠层器件稳定性的主要因素，包括钙钛矿材料的热稳定性、界面缺陷与非辐射复合、离子迁移行为以及光照、温度和湿度等外界环境因素。随后重点总结了当前提升器件稳定性的主要策略，如采用组分工程调控钙钛矿晶体结构、界面钝化与界面工程优化、电荷传输层稳定性提升以及采用器件封装技术等。同时，对不同稳定性测试条件与评价标准进行了归纳比较，以揭示器件性能衰减的主要机理。综合现有研究结果可以看出，通过合理的材料设计与界面调控能够有效抑制缺陷态和离子迁移，从而显著提升叠层器件的运行稳定性。最后，对钙钛矿/硅叠层太阳能电池稳定性研究中仍面临的挑战进行了讨论，并对未来的发展方向进行了展望，以期为实现高效率、长寿命叠层光伏器件的进一步发展提供参考。
Abstract:
In recent years, perovskite/silicon tandem solar cells have become a research hotspot in the field of photovoltaics due to their ability to surpass the efficiency limit of single-junction photovoltaic devices. However, compared to the rapid improving of photovoltaic conversion efficiency, the insufficient device stability remains a key factor limiting their large-scale application. Regarding the insufficient stability issues of perovskite/silicon tandem solar cells, a systematic review of the recent research progress has been conducted. Firstly, the main factors affecting the stability of the tandem devices were analyzed, including the thermal stability of perovskite materials, interface defects and nonradiative recombination, ionic migration behavior, and external environmental factors such as light, temperature and humidity. Subsequently, the main strategies for improving the device stability were summarized, including the use of component engineering to control the crystal structure of perovskite,interface passivation and interface engineering optimization,improvement of charge transport layer stability and the use of device packaging technology. At the same time, different stability testing conditions and evaluation criteria were summarized and compared to reveal the main mechanisms of device degradation. Based on the existing research results, it can be seen that through reasonable material design and interface control, defect states and ionic migration can be effectively suppressed, thereby significantly improving the operational stability of the tandem devices. Finally, the challenges still faced in the stability research of perovskite/silicon tandem solar cells were discussed, and the future development direction was prospected, with the aim of providing a reference for the further development of high-efficiency and long-life tandem photovoltaic devices.

备注/Memo

备注/Memo:
收稿日期：2026-04-09修回日期：2026-05-16 基金项目：国家科技重大专项（2022YFB4200203）；国家自然科学基金资助项目（62174114，U24A2063）；江苏省基础研究计划重点项目（BK20243031）;江苏省科学技术厅资助项目（BE2022023，BE2022027） 第一作者：王畅，男，1997年生，博士研究生 通讯作者：杨新波，男，1982年生，教授，博士生导师， Email: xbyang@suda.edu.cn
更新日期/Last Update: 2026-06-02