[1]陈睿豪 张钧硕 戴小康 刘宇轩等。.绿色溶剂在钙钛矿太阳能电池中的研究进展与应用[J].中国材料进展,2026,45(10):040-49.
　CHEN Ruihao,ZHANG Junshuo,DAI Xiaokang,et al.Research and Application Status of Perovskite Solar Cell Green Solvents[J].MATERIALS CHINA,2026,45(10):040-49.
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绿色溶剂在钙钛矿太阳能电池中的研究进展与应用()

中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
45
期数:
2026年10
页码:
040-49
栏目:
出版日期:
2026-09-30

文章信息/Info

Title:
Research and Application Status of Perovskite Solar Cell Green Solvents
作者:
陈睿豪 张钧硕 戴小康 刘宇轩等。
西北工业大学 材料学院，陕西 西安 710012
Author(s):
CHEN Ruihao;  ZHANG Junshuo;  DAI Xiaokang;  LIU Yuxuan; et al.
School of Material Science and Engineering, Northwestern Polytechnical University, Xi’an 710012, China
关键词:
新能源材料; 钙钛矿太阳能电池; 绿色溶剂; 制备方法; 溶剂毒性
Keywords:
new energy materials;  perovskite solar cells;  green solvents;  preparation methods;  solvent toxicity
文献标志码:
A
摘要:
高效的钙钛矿太阳能电池的生产制备工艺离不开溶剂的使用，但其主流制备工艺所用溶剂，诸如N,N-二甲基甲酰胺（DMF）、氯苯（CB）等，都含有严重的环境或生物毒性，严重阻碍了钙钛矿的绿色制备，成为其商业化制备一大障碍。鉴于此，寻找合适的绿色溶剂被重视起来，以期降低环境足迹和职业健康风险，达到绿色环保生产的目的。本文首先对现有钙钛矿绿色溶剂体系分为绿色前驱体溶剂、绿色反溶剂、辅助添加剂和混合溶剂体系四类，并在分类的基础上总结各类溶剂的特性和亮点，评估其在钙钛矿太阳能电池制备中的作用和功效。然后，总结了绿色溶剂在钙钛矿合成中的具体应用策略。最后，本文总结了钙钛矿绿色溶剂现存的关键问题，并对其未来创新解决方案提供了展望。本文旨在为钙钛矿太阳能电池的绿色制备提供溶剂选择上的参考，并为绿色溶剂的后续开发提供思路，助力钙钛矿太阳能电池的大规模绿色制备。
Abstract:
The fabrication of high-performance perovskite solar cells (PSCs) inherently relies on solvent-based processing. However, conventional methods predominantly employ hazardous solvents, including N,N-dimethylformamide (DMF) and chlorobenzene (CB), which has severe ecological and biological risks, undermines sustainable manufacturing pathways and represents a critical bottleneck for industrial-scale deployment. To address this challenge, the search for suitable green solvents has gained importance in order to reduce environmental impact and occupational health risks, thereby achieving environmentally friendly production. This review systematically organizes currently explored green solvents for perovskite processing into four distinct groups: (i) green precursor solvents, (ii) green anti-solvents, (iii) auxiliary additives, (iv) mixed solvent systems. For each category, we analyze physicochemical properties, processing advantages, and functional contributions to film formation, crystallization control, and device performance.Then, this review further outlines practical implementation approaches, such as solvent engineering, sequential deposition, and additive-assisted crystallization. In the end, this review critically examines recent key problems of perovskite green solvents, including limited solubility of precursors, poor film uniformity,scalability constraints, long-term stability concerns, and proposes forward-looking directions. This article aims to offer references to solvent selection for green fabrication of PSCs and provide ideas for green solvents’ future development to support large-scale green fabrication of PSCs.
更新日期/Last Update: 2026-08-31