[1]董俊卿,李青会,干福熹,等.一批河南出土东周至宋代玻璃器的无损分析[J].中国材料进展,2012,(11):009-15.[doi:10.7502/j.issn.1674-3962.2012.11.02]
　DONG Junqing,LI Qinghui,GAN Fuxi,et al.Non Destructive Analysis of Some Glass Artifacts Dated from Eastern Zhou to Song Dynasty Unearthed from Henan Province[J].MATERIALS CHINA,2012,(11):009-15.[doi:10.7502/j.issn.1674-3962.2012.11.02]
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一批河南出土东周至宋代玻璃器的无损分析()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
期数:
2012年第11期
页码:
009-15
栏目:
特约研究论文
出版日期:
2012-11-30

文章信息/Info

Title:
Non Destructive Analysis of Some Glass Artifacts Dated from Eastern Zhou to Song Dynasty Unearthed from Henan Province
作者:
董俊卿; 李青会; 干福熹; 胡永庆; 程永建; 蒋宏杰
（1中国科学院上海光学精密机械研究所科技考古中心，上海201800）
（2河南省文物考古研究所，河南 郑州 450000）
（3洛阳文物考古研究院，河南 洛阳 471000）
（4南阳市文物考古研究所，河南 南阳 473000）
Author(s):
DONG Junqing; LI Qinghui; GAN Fuxi; HU Yongqing; CHENG Yongjian; JIANG Hongjie
(1 Center of Scitech Archaeology, Shanghai Institute of Optics and Fine Mechanics,CAS, Shanghai 201800, China)
(2 Provincial Institute of Cultural Relics and Archeology of Henan, Zhengzhou 450000, China)
(3 Luoyang Municipal Institute of Cultural Relics, Luoyang 471000, China)
(4 Municipal Institute of Cultural Relics and Archeology of Nanyang, Nanyang 473000, China)
关键词:
古代玻璃; 化学成分体系; 无损分析
DOI:
10.7502/j.issn.1674-3962.2012.11.02
摘要:
为探索古代中原地区早期玻璃器的技术起源、发展和成分体系，选取了河南新郑、南阳、荥阳和洛阳等地出土的一批东周至宋代的26件古代玻璃器及1件汉代釉陶器，利用外束PIXE和pXRF对其进行了无损分析。分析结果表明，不同时代玻璃器的化学成分体系存在一定差异。东周时期有Na2OCaOSiO2和PbOBaOSiO2两种体系；汉代有PbOBaOSiO2、PbOSiO2和K2OCaOSiO2 3种体系；唐、宋时期则有Na2OCaOSiO2和PbOK2OSiO2两种体系。结合以往研究成果，讨论了器物来源、风化对定量分析的影响以及主要的着色离子等相关问题。其中，Na2OCaOSiO2体系玻璃为西方舶来品，其他系统的玻璃器为我国自制。由于表面风化，不同成分体系的古代玻璃都存在主要助熔剂的流失现象，流失程度与样品风化程度密切相关。这些玻璃的不同着色特征，与过渡金属元素密切相关。研究为探讨早期中外玻璃贸易和技术交流，以及中国古代玻璃的起源与发展提供了新的科学依据。
Abstract:
To trace the technological origin, development and chemical composition system, in the present research, a total of 26 glass artifacts and 1 glazed pottery of the Han Dynasty were analyzed non destructively by means of external beam proton induced X ray emission (PIXE) and portable energy dispersive X ray fluorescence (p XRF) spectroscopy. These ancient glass artifacts dated from the Eastern Zhou to the Song Dynasty were unearthed from Xinzheng, Nanyang, Xingyang, Luoyang and other cities in Henan province. It is found that the chemical composition systems of these glass artifacts showed some different characteristics in different historic periods. During the Eastern Zhou, there were Na2OCaO SiO2 and PbO BaO SiO2 glasses. PbOBaOSiO2, PbOSiO2 and K2OCaOSiO2 glasses were found in the Han Dynasty. While in the Tang and Song Dynasties, both Na2OCaOSiO2 and PbOK2OSiO2 glasses were identified. Among them, the Na2OCaOSiO2 glasses were imported from the West and the others were native products of China. The main fluxes used in these ancient glasses were lost with different amount depending on the level of the surface weather. The versatile colors of these glasses were related to different transition metal elements. The results obtained provided some new clues to trace the early glasses trade and technical exchanges between China and abroad, and also to understand the origin and development of ancient Chinese glasses.
更新日期/Last Update: 2012-11-07