[1]张雅静,卞兆勇.单原子催化剂中金属-载体强相互作用综述[J].中国材料进展,2023,42(04):328-334.[doi:10.7502/j.issn.1674-3962.202103031]
　ZHANG Yajing,BIAN Zhaoyong.A Review of the Strong Metal-Support Interactions in Single-Atom Catalysts[J].MATERIALS CHINA,2023,42(04):328-334.[doi:10.7502/j.issn.1674-3962.202103031]
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单原子催化剂中金属-载体强相互作用综述()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
42
期数:
2023年第04期
页码:
328-334
栏目:
出版日期:
2023-04-30

文章信息/Info

Title:
A Review of the Strong Metal-Support Interactions in Single-Atom Catalysts
文章编号:
1674-3962(2023)04-0328-07
作者:
张雅静; 卞兆勇
北京师范大学 水科学研究院，北京 100875
Author(s):
ZHANG Yajing;  BIAN Zhaoyong
College of Water Sciences, Beijing Normal University, Beijing 100875, China
关键词:
单原子催化; 金属-载体强相互作用; 多相催化; 缺陷; 配位
Keywords:
single-atom catalysis;  strong metal-support interaction;  heterogeneous catalysis;  defect;  coordination
分类号:
O643
DOI:
10.7502/j.issn.1674-3962.202103031
文献标志码:
A
摘要:
单原子催化由于其独特的特性近年来在多相催化领域引发很大的关注。均匀分散的单原子可以作为催化活性中心，为实现催化反应的高选择性、高活性和研究其催化反应机理提供很大的可能。随着催化剂尺寸的逐步减小，催化剂的表面原子结构、电子结构和缺陷将发生明显变化，常常会产生金属-载体强相互作用。结合近年来单原子催化领域的研究工作，综述了单原子催化剂中金属-载体强相互作用的研究进展。介绍了单原子催化剂中金属-载体强相互作用的具体类型和表现形式，包括金属-金属相互作用、空隙或缺陷锚定、金属阳离子配位和有机配体络合。最后，基于对单原子催化剂中金属-载体强相互作用的理解和认识，对该研究领域的发展趋势和关键问题进行了展望。
Abstract:
Single-atom catalysis has gained more and more attention in the field of heterogeneous catalysis in recent years. As the catalytic activity center, uniform and dispersed single atom provides great possibility for the realization of high activity and selectivity of catalytic reaction and to study their catalytic reaction mechanisms. With the gradual decreasing of the catalyst size, the surface atomic structure, electronic structure and defect of catalyst are significantly changed, often resulting in strong metal-support interactions. Based on the previous research works in recent years, the strong metal-support interactions in single-atom catalyst are summarized in this paper. The specific types and forms of strong metal-support interactions in a single-atom catalyst are introduced, including metal-metal interactions, vacancy or defect anchoring, metal cation coordination and organic ligand complexation. Furthermore, based on the understanding and knowledge of strong metal-support interactions in single-atom catalysis, the development trends and key issues in this field are prospected.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期：2021-03-28修回日期：2021-08-17 基金项目：国家自然科学基金资助项目（21872009） 第一作者：张雅静，女，1997年生，硕士研究生 通讯作者：卞兆勇，男，1978年生，教授，博士生导师， Email: bian@bnu.edu.cn
更新日期/Last Update: 2023-03-22