[1]李波,张树朝,瞿媛媛.铝灰检测技术研究进展[J].中国材料进展,2023,42(10):833-839.[doi:10.7502/j.issn.1674-3962.202108037]
 LI Bo,ZHANG Shuchao,QU Yuanyuan.Research Progress of the Test Technology of Aluminum Dross[J].MATERIALS CHINA,2023,42(10):833-839.[doi:10.7502/j.issn.1674-3962.202108037]
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铝灰检测技术研究进展()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
42
期数:
2023年第10期
页码:
833-839
栏目:
出版日期:
2023-10-31

文章信息/Info

Title:
Research Progress of the Test Technology of Aluminum Dross
文章编号:
1674-3962(2023)10-0833-07
作者:
李波张树朝瞿媛媛
中铝郑州有色金属研究院有限公司,河南 郑州 450041
Author(s):
LI Bo ZHANG Shuchao QU Yuanyuan
Zhengzhou Non-Ferrous Metals Research Institute Co, Ltd, of CHALCO,Zhengzhou 450041,China
关键词:
铝灰检测技术X射线荧光光谱法湿法化学分析X射线衍射法Rietveld全谱拟合
Keywords:
aluminum dross test technology X-ray fluorescence spectrometry wet chemical analysis X-ray diffraction method Rietveld full spectrum fitting
分类号:
X758
DOI:
10.7502/j.issn.1674-3962.202108037
文献标志码:
A
摘要:
铝灰已被列入国家危险废物名录,属于HW48有色金属采选与冶炼废物,需按照危险废物管理的相关规定进行处置。不同来源(铝冶炼、铝加工、废铝回收)的铝灰性能、成分差别很大,检测方法无法统一,需要根据样品情况研究确定。为此,很多学者利用X射线荧光光谱法半定量、湿法化学分析、电感耦合等离子体-原子发射光谱法、原子吸收光谱法、X射线衍射法物相定性等测试方法做了大量的研究工作,发表了各自的研究成果,也起草了几个行业标准。但一些论文、标准考虑不够全面,提出的测试方法有待商榷。为了使从事铝灰处置的技术人员更加全面地了解铝灰成分的测试方法,系统分析这些方法的优点及存在的不足,同时提出通过Rietveld全谱拟合对铝灰进行定量分析的方法,为原铝灰、无害化处理后铝灰的分析检测提供了一种新的思路。
Abstract:
Aluminum dross has been included in the national hazardous waste list and belongs to HW48 nonferrous metal mining and smelting waste, which needs to be disposed in accordance with the relevant regulations of hazardous waste management. The performance and composition of aluminum dross from different sources (aluminum smelting, aluminum processing, waste aluminum recovery) vary greatly, so there is no mature detection method for reference,which needs to be studied based on the sample. Therefore, many scholars have done a lot of researches by using X-ray fluorescence spectrometry semi-quantitative, wet chemical analysis, inductively coupled plasma-atomic emission spectrometry, atomic absorption spectrometry, X-ray diffraction phase qualitative and other testing methods; published their own research results and drafted several industry standards. However, due to the insufficient consideration of individual standards and individual scholars, the test methods proposed are worth discussing. In order to enable the technical personnel engaged in aluminum dross disposal to have a more comprehensive understanding of the testing methods of aluminum dross, this paper systematically analyzes the advantages and disadvantages of the above methods, and proposes the method of Rietveld full spectrum fitting for quantitative analysis of aluminum dross, which provides a new idea for the analysis and detection of primary aluminum dross and aluminum dross after harmless treatment.

参考文献/References:

\[1\]康天宇.铝灰处理与循环利用研究\[D\].沈阳:东北大学,2011. KANG T Y.Study on Treatment and Recycling of Aluminum Dross\[D\].Shenyang:Northeastern University,2011. \[2\]张庆建,丁仕兵,冯丽丽,等.分析测试学报\[J\],2012,31(Z1):219-221. ZHANG Q J,DING S B,FENG L L,et al.Journal of Instrumental Analysis\[J\],2012,31(Z1): 219-221. \[3\]杨航,申士富,刘海营,等.有色金属工程\[J\],2019,9(10):117-124. YANG H,SHEN S F,LIU H Y,et al.Nonferrous Metals Engineering\[J\],2019,9(10): 117-124. \[4\]GALINDO R,PADILLA I,RODRGUEZ O,et al.Journal of Minerals and Materials Characterization and Engineering\[J\],2015,3(2):55-64. \[5\]LI Q,YANG Q,ZHANG G,et al.Hydrometallurgy\[J\],2018,182:121-127. \[6\]BEHESHTI R,MOOSBERGBUSTNES J,AKHTAR S,et al.JOM: the Journal of the Minerals, Metals & Materials Society\[J\],2014,66(11):2243-2252. \[7\]吕景华,刘静,闫琳.内蒙古农业大学学报(自然科学版)\[J\],2004,25(1):25-30. LV J H,LIU J,YAN L.Journal of Inner Mongolia Agricultural University(Natural Science Edition)\[J\],2004,25(1): 25-30. \[8\]张晨.中国无机分析化学\[J\],2020,10(5):24-27. ZHANG C.Chinese Journal of Inorganic Analytical Chemistry\[J\],2020,10(5): 24-27. \[9\]LUCHEVA B,TSONEV T,PETKOV R.Journal of the University of Chemical Technology and Metallurgy\[J\],2005,40(4):335-338. \[10\]中华人民共和国国家质量监督检验检疫总局.钢铁氮含量的测定 惰性气体熔融热导法(常规方法):GB/T20124—2006\[S\].北京:中国标准出版社,2006. General Administration of Quality Supervision, Inspection and Quarantine of the Peoples Republic of China.Steel and IronDetermination of Nitrogen ContentThermal Conductimetric Method after Fusion in a Current of Inert Gas(Roution Method):GB/T20124—2006\[S\].Beijing:Standards Press of China,2006. \[11\]中华人民共和国工业和信息化部.钢铁及合金氮含量的测定 惰性气体熔融热导法:YB/T4306—2012\[S\].北京:冶金工业出版社,2012. Ministry of Industry and Information Technology of the Peoples Republic of China.Steel, Iron and AlloyDetermination of Nitrogen ContentThermal Conductimetric Method after Fusion in a Current of Inert Gas: YB/T4306—2012\[S\].Beijing:Metallurgical Industry Press,2012. \[12\]丛琳琳,王凡,金英,等.化学分析计量\[J\],2020,29(S1):63-66. CONG L L,WANG F,JIN Y,et al.Chemical Analysis and Meterage\[J\],2020,29(S1): 63-66. \[13\]INGASON H T,SIGFUSSON T.JOM: the Journal of the Minerals, Metals & Materials Society\[J\],2014,66(11):2235-2242. \[14\]LI P,GUO M,ZHANG M.Mineral Processing & Extractive Metallurgy\[J\],2012,121(3):140-146. \[15\]王皖红,王锝,李晓怡.资源环境与工程\[J\],2009,23(3):333-334. WANG W H,WANG D,LI X Y.Resources Environment & Engineering\[J\],2009,23(3): 333-334. \[16\]王剑云,王雪红,张光爽.浙江冶金\[J\],2012(2):22-24. WANG J Y,WANG X H,ZHANG G S.Journal of Zhejiang Metallurgy\[J\],2012(2): 22-24. \[17\]FUKUMOTO S,HOOKABE T,TSUBAKINO H.Journal of Materials Science\[J\],2000,35(11):2743-2748. \[18\]姜澜,邱明放,丁友东,等.中国有色金属学报\[J\],2012,22(12):3555-3561. JIANG L,QIU M F,DING Y D,et al.The Chinese Journal of Nonferrous Metals\[J\],2012,22(12): 3555-3561. \[19\]刘吉.铝灰渣性质及其中的AlN在焙烧和水解过程中的行为研究\[D\].沈阳:东北大学,2008. LIU J.Study on the Properties of Aluminum Dross and the Behavior of AlN in it During Roasting and Hydrolysis\[D\].Shenyang:Northeastern University,2008. \[20\]林芳.中国石油和化工标准与质量\[J\],2014(21):15. LIN F.China Petroleum and Chemical Standard and Quality\[J\],2014(21): 15. \[21\]丛琳琳,王凡,田小亭,等.冶金分析\[J\],2018,38(11):43-47. CONG L L,WANG F,TIAN X T,et al.Metallurgical Analysis\[J\],2018,38(11): 43-47. \[22\]杨忠梅,李静.冶金分析\[J\],2020,40(9):87-91. YANG Z M,LI J.Metallurgical Analysis\[J\],2020,40(9): 87-91. \[23\]程宏伟.新疆有色金属\[J\],2014,37(S2):135-136. CHENG H W.Xinjiang NonFerrous Metals\[J\],2014,37(S2): 135-136. \[24\]韦京汝,卢燕平.科学与财富\[J\],2015(9):619-620. WEI J R,LU Y P.Science and Wealth\[J\],2015(9): 619-620. \[25\]吕长宽,秦群,施意华,等.矿产与地质\[J\],2020,34(3):638-643. LV C K,QIN Q,SHI Y H,et al.Mineral Resources and Geology\[J\],2020,34(3): 638-643. \[26\]刘兰,余志峰,拉毛吉,等.中国标准化\[J\],2018(19):170-173. LIU L,YU Z F,LA M J,et al.China Standardization\[J\],2018(19): 170-173. \[27\]朱小凡,欧玉静,朱江凯,等.甘肃科技\[J\],2019,35(20):14-18. ZHU X F,OU Y J,ZHU J K,et al.Gansu Science and Technology\[J\],2019,35(20): 14-18. \[28\]张悦清,何欣凌,豆叶枝,等.铝工业链中铝灰渣固体废物浸出毒性特征与管理要求\[C\]//中国环境科学学会科学技术年会论文集(第二卷).北京:中国科学技术出版社,2020:1164-1169. ZHANG Y Q,HE X L,DOU Y Z,et al.Leaching Toxicity Characteristics and Management Requirements of Aluminum Dross Slag Solid Waste in Aluminum Industry Chain\[C\]//Proceedings of Annual Conference of Chinese Society for Environmental Science (Vol2).Beijing:China Science and Technology Press,2020:1164-1169. \[29\]戴翔,焦少俊,郑洋,等.无机盐工业\[J\],2018,50(11):42-44. DAI X,JIAO S J,ZHENG Y,et al.Inorganic Chemicals Industry\[J\],2018,50(11): 42-44. \[30\]焦志伟,刘伟,张涛,等.现代交通与冶金材料\[J\],2019,47(4):19-21. JIAO Z W,LIU W,ZHANG T,et al.Modern Transportation and Metallurgical Materials\[J\],2019,47(4): 19-21. \[31\]BISH D L,POST J E.国外矿床地质\[J\],1995(2):31-41. BISH D L,POST J E.Mineral Geology Abroad\[J\],1995(2): 31-41. \[32\]马礼敦.近代X射线多晶体衍射:实验技术与数据分析\[M\].北京:化学工业出版社,2004. MA L D.Recent Xray Polycrystalline Diffraction: Experimental Techniques and Data Analysis\[M\].Beijing: Chemical Industry Press, 2004.

备注/Memo

备注/Memo:
收稿日期:2021-08-27修回日期:2022-02-10 第一作者:李波,男,1980年生,正高级工程师, Email: zyy_libo@rilm.com.cn
更新日期/Last Update: 2023-09-28