[1]茹鲜古丽·艾外力,热娜古丽·阿不都热合曼.稀土掺杂长余辉纳米材料研究简述[J].中国材料进展,2023,42(08):649-656.[doi:10.7502/j.issn.1674-3962.202109030]
　AWAL Ruxangul,ABDURAHMAN Renagul.Brief Introduction on the Study of Rare Earth Doped Persistent Luminescence Nanoparticles[J].MATERIALS CHINA,2023,42(08):649-656.[doi:10.7502/j.issn.1674-3962.202109030]
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稀土掺杂长余辉纳米材料研究简述()
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中国材料进展[ISSN:1674-3962/CN:61-1473/TG]

卷:
42
期数:
2023年第08期
页码:
649-656
栏目:
出版日期:
2023-08-31

文章信息/Info

Title:
Brief Introduction on the Study of Rare Earth Doped Persistent Luminescence Nanoparticles
文章编号:
1674-3962(2023)08-0649-08
作者:
茹鲜古丽·艾外力; 热娜古丽·阿不都热合曼
喀什大学化学与环境科学学院 新疆特色药食用植物资源化学实验室，新疆 喀什 844006
Author(s):
AWAL Ruxangul;  ABDURAHMAN Renagul
Laboratory of Xinjiang Native Medicinal and Edible Plant Resources Chemistry,College of Chemistry and Environmental Science, Kashi University, Kashi 844006, China
关键词:
稀土元素; 长余辉纳米粒子; 镧系元素; 余辉强度; 发光中心
Keywords:
rare earth elements;  persistent luminescent nanoparticles;  lanthanides; afterglow intensity;  luminescence center
分类号:
TB383
DOI:
10.7502/j.issn.1674-3962.202109030
文献标志码:
A
摘要:
长余辉纳米粒子（persistent luminescence nanoparticles, PLNPs）是一种特殊的发光材料，具有很长的余辉时间。尤其是稀土元素（rare earth elements, REE）掺杂PLNPs（REE-PLNPs）具有独特的4f电子构型、优异的物理化学稳定性、高的发光强度和量子产率以及长的余辉时间。通过调节REE掺杂离子的种类和浓度，可以改变REE-PLNPs的发射波长范围。虽然发光中心相同，但由于不同材料所属的晶格不同，不同PLNPs基质材料的光学性质往往不同。因此，改变基质材料以及稀土共掺杂离子的种类，以提高REE-PLNPs的发光强度，进而可对余辉性能进行优化，故REE-PLNPs在室内装修、安全标志、仪表显示、生物检测和成像、诊疗一体化等领域受到了研究者的关注。以镧系元素和Sc与Y等掺杂REE-PLNPs为例，介绍了REE-PLNPs的组成和余辉发光性能及其在光学性质方面的研究进展。评述了REE在改善PLNPs的发射波长和余辉强度方面的优势，展望了REE-PLNPs研究未来的发展方向。
Abstract:
Persistent luminescence nanoparticles (PLNPs) are special luminescent materials with long afterglow time. In particular, rare earth elements (REE) doped PLNPs (REE-PLNPs) possess unique 4f electron configuration, excellent physical and chemical stability, high luminescence intensity, quantum yield, and long afterglow time. The emission wavelength range of REE-PLNPs can be changed by adjusting REE ion species and doping element concentration.Although the luminescence centers are the same, different PLNPs matrix materials often have different optical properties due to the different lattices to which the different materials belong. Therefore, the luminescence intensity of REE-PLNPs can be improved by changing the type of matrix materials and rare earth co-doped ions, and then the afterglow performance can be optimized. Therefore, REEPLNPs has attracted the attention of researchers in the fields of interior decoration, safety sign, instrument display, biological detection and imaging, and integration of diagnosis and treatment.The composition and afterglow luminescence properties of REE-PLNPs, including lanthanide elements and Sc and Y, are reviewed. The advantages of REE in improving the emission wavelength and afterglow intensity of PLNPs are also reviewed, and the future development direction of REE-PLNPs research is prospected.

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备注/Memo

备注/Memo:
收稿日期：2021-09-24修回日期：2021-12-22 基金项目：国家自然科学基金项目(21867014)；新疆维吾尔自治区自然科学基金资助项目（2018D01A05）；新疆维吾尔自治区“天山青年”计划科技人才培养项目(2017Q086）；喀什大学高层次人才科研启动经费项目（GCC18ZK-003）；喀什大学博士专项（（16）2579） 第一作者：茹鲜古丽·艾外力，女，1996年生，硕士 通讯作者：热娜古丽·阿不都热合曼，女，1985年生，副教授，硕士生导师，Email：renagul111@aliyun.com
更新日期/Last Update: 2023-07-28